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author:

Li, Wangyang (Li, Wangyang.) [1] (Scholars:李王阳) | Deng, Liying (Deng, Liying.) [2] | Cao, Jiaqi (Cao, Jiaqi.) [3] | Ke, Bingyuan (Ke, Bingyuan.) [4] | Wang, Xinghui (Wang, Xinghui.) [5] (Scholars:王星辉) | Ni, Shibing (Ni, Shibing.) [6] | Cheng, Shuying (Cheng, Shuying.) [7] (Scholars:程树英) | Lu, Bingan (Lu, Bingan.) [8]

Indexed by:

EI Scopus SCIE

Abstract:

Beyond the high theoretical capacity, conversion-alloying metal chalcogenides (CAMCs) exhibit exceptional high-rate performance as Li-ion battery electrodes. However, the inherent origin of the high-rate performance remains elusive, especially given the lower intrinsic conductivity of CAMCs. Here, the correlation between phase evolution and charge transport dynamics in fully activated CAMCs is systematically investigated, elucidating a current-adaptive Li-ion storage mechanism to explain the anomalous high-rate performance. Briefly, the deconversion reaction manipulated by ion diffusion acts as a "regulator" to adaptively modulate the transition from metal (high electronic conductivity) and lithium chalcogenides (high ionic conductivity) to CAMCs, thus removing the charge transport bottleneck without affecting the formation of the metal feedstock required for the alloying reaction. On this basis, the high capacity can be maintained at high rates through a "fading-free" alloying reaction. This study offers a novel perspective for the design of high-rate electrode materials. The high-rate performance of conversion-alloying metal chalcogenides is accomplished through a current-adaptive mechanism: they autonomously adjust their conversion/deconversion reactivity at high rates to enhance charge transport and achieve a "fading-free" alloying/dealloying reaction, akin to the self-protection mechanism observed in lizards. image

Keyword:

alloying conversion current-adaptive high rate Li-ion battery

Community:

  • [ 1 ] [Li, Wangyang]Fuzhou Univ, Inst Micronano Devices & Solar Cells, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China
  • [ 2 ] [Cao, Jiaqi]Fuzhou Univ, Inst Micronano Devices & Solar Cells, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China
  • [ 3 ] [Ke, Bingyuan]Fuzhou Univ, Inst Micronano Devices & Solar Cells, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China
  • [ 4 ] [Wang, Xinghui]Fuzhou Univ, Inst Micronano Devices & Solar Cells, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China
  • [ 5 ] [Cheng, Shuying]Fuzhou Univ, Inst Micronano Devices & Solar Cells, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China
  • [ 6 ] [Deng, Liying]Fujian Agr & Forestry Univ, Coll Mech & Elect Engn, Shangxiadian Rd 15, Fuzhou 350002, Peoples R China
  • [ 7 ] [Wang, Xinghui]Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350108, Fujian, Peoples R China
  • [ 8 ] [Wang, Xinghui]Jiangsu Collaborat Innovat Ctr Photovolta Sci & En, Changzhou 213000, Peoples R China
  • [ 9 ] [Cheng, Shuying]Jiangsu Collaborat Innovat Ctr Photovolta Sci & En, Changzhou 213000, Peoples R China
  • [ 10 ] [Ni, Shibing]China Three Gorges Univ, Coll Mat & Chem Engn, Key Lab Inorgan Nonmet Crystalline & Energy Conver, Yichang 443002, Peoples R China
  • [ 11 ] [Cheng, Shuying]Fuzhou Univ, Fujian Key Lab Electrochem Energy Storage Mat, Fuzhou 350002, Fujian, Peoples R China
  • [ 12 ] [Lu, Bingan]Hunan Univ, Sch Phys & Elect, Changsha 410082, Peoples R China

Reprint 's Address:

  • [Wang, Xinghui]Fuzhou Univ, Inst Micronano Devices & Solar Cells, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China;;[Cheng, Shuying]Fuzhou Univ, Inst Micronano Devices & Solar Cells, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China;;[Wang, Xinghui]Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350108, Fujian, Peoples R China;;[Wang, Xinghui]Jiangsu Collaborat Innovat Ctr Photovolta Sci & En, Changzhou 213000, Peoples R China;;[Cheng, Shuying]Jiangsu Collaborat Innovat Ctr Photovolta Sci & En, Changzhou 213000, Peoples R China;;[Cheng, Shuying]Fuzhou Univ, Fujian Key Lab Electrochem Energy Storage Mat, Fuzhou 350002, Fujian, Peoples R China;;

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Source :

ADVANCED FUNCTIONAL MATERIALS

ISSN: 1616-301X

Year: 2024

Issue: 44

Volume: 34

1 8 . 5 0 0

JCR@2023

Cited Count:

WoS CC Cited Count: 6

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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