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author:

Min, Shihao (Min, Shihao.) [1] | Wang, Zhuoyue (Wang, Zhuoyue.) [2] | Xu, Xiao (Xu, Xiao.) [3] | He, Jiaxin (He, Jiaxin.) [4] | Sun, Miao (Sun, Miao.) [5] | Lin, Wenlie (Lin, Wenlie.) [6] | Kang, Longtian (Kang, Longtian.) [7]

Indexed by:

EI Scopus SCIE

Abstract:

The transition metal (Fe, Co, Ni)-doped cuprous oxide (Cu2O) nanowire arrays on Cu mesh (CM) (M-Cu2O@CM, M = Fe, Co, Ni) are successfully synthesized for the electrocatalytic CO2 reduction reaction (CO2RR) to ethylene (C2H4) through the simple calcination and impregnation-exchange methods. Systematic characterizations have demonstrated that the Ni/Co doping in Cu2O@CM is conducive to stabilizing the Cu+ sites due to the electron transfer from Cu2O to Ni/Co, while the Fe doping has the opposite effect. Consequently, they show the different electrocatalytic performances of Ni-Cu2O@CM > Co-Cu2O@CM > Cu2O@CM > Fe-Cu2O@CM for CO2RR to C2H4 in an H-cell. Among them, Ni-Cu2O@CM exhibits the similar to 2.0-fold faradaic efficiency for C2H4 (58.2 % vs. 28.7 %) and the similar to 2.5-fold current density (-37.6 vs. -15.0 mAcm(-2)) at -1.1 V vs. RHE, as compared with Cu2O@CM. Further experiments reveal that during the electrocatalytic CO2RR, the Ni-Cu2O@CM can generate more *CO, which promotes the C-C coupling reaction. The activity of Co-Cu2O@CM is lower than Ni-Cu2O@CM because of the strong adsorption of *COOH, while the Fe-Cu2O@CM even exhibits a lower activity than Cu2O@CM. This work provides an insight into the effect of transition metal-doped Cu2O array on the electrocatalytic CO2RR to C2H4 products.

Keyword:

Array CO2 reduction Cuprous oxide Ethylene Transition metal

Community:

  • [ 1 ] [Min, Shihao]Fuzhou Univ, Coll Chem, Fuzhou 350116, Peoples R China
  • [ 2 ] [Wang, Zhuoyue]Fuzhou Univ, Coll Chem, Fuzhou 350116, Peoples R China
  • [ 3 ] [He, Jiaxin]Fuzhou Univ, Coll Chem, Fuzhou 350116, Peoples R China
  • [ 4 ] [Min, Shihao]Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Fujian, Peoples R China
  • [ 5 ] [Wang, Zhuoyue]Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Fujian, Peoples R China
  • [ 6 ] [Xu, Xiao]Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Fujian, Peoples R China
  • [ 7 ] [He, Jiaxin]Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Fujian, Peoples R China
  • [ 8 ] [Sun, Miao]Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Fujian, Peoples R China
  • [ 9 ] [Lin, Wenlie]Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Fujian, Peoples R China
  • [ 10 ] [Kang, Longtian]Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Fujian, Peoples R China
  • [ 11 ] [Min, Shihao]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Prov Key Lab Nanomat, Fuzhou 350002, Fujian, Peoples R China
  • [ 12 ] [Wang, Zhuoyue]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Prov Key Lab Nanomat, Fuzhou 350002, Fujian, Peoples R China
  • [ 13 ] [Xu, Xiao]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Prov Key Lab Nanomat, Fuzhou 350002, Fujian, Peoples R China
  • [ 14 ] [He, Jiaxin]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Prov Key Lab Nanomat, Fuzhou 350002, Fujian, Peoples R China
  • [ 15 ] [Sun, Miao]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Prov Key Lab Nanomat, Fuzhou 350002, Fujian, Peoples R China
  • [ 16 ] [Lin, Wenlie]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Prov Key Lab Nanomat, Fuzhou 350002, Fujian, Peoples R China
  • [ 17 ] [Kang, Longtian]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Prov Key Lab Nanomat, Fuzhou 350002, Fujian, Peoples R China
  • [ 18 ] [Min, Shihao]Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350108, Fujian, Peoples R China
  • [ 19 ] [Wang, Zhuoyue]Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350108, Fujian, Peoples R China
  • [ 20 ] [Xu, Xiao]Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350108, Fujian, Peoples R China
  • [ 21 ] [He, Jiaxin]Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350108, Fujian, Peoples R China
  • [ 22 ] [Sun, Miao]Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350108, Fujian, Peoples R China
  • [ 23 ] [Lin, Wenlie]Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350108, Fujian, Peoples R China
  • [ 24 ] [Kang, Longtian]Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350108, Fujian, Peoples R China
  • [ 25 ] [Min, Shihao]Univ Chinese Acad Sci, Fujian Coll, Fuzhou 350002, Peoples R China
  • [ 26 ] [Wang, Zhuoyue]Univ Chinese Acad Sci, Fujian Coll, Fuzhou 350002, Peoples R China
  • [ 27 ] [Xu, Xiao]Univ Chinese Acad Sci, Fujian Coll, Fuzhou 350002, Peoples R China
  • [ 28 ] [He, Jiaxin]Univ Chinese Acad Sci, Fujian Coll, Fuzhou 350002, Peoples R China
  • [ 29 ] [Sun, Miao]Univ Chinese Acad Sci, Fujian Coll, Fuzhou 350002, Peoples R China
  • [ 30 ] [Lin, Wenlie]Univ Chinese Acad Sci, Fujian Coll, Fuzhou 350002, Peoples R China
  • [ 31 ] [Kang, Longtian]Univ Chinese Acad Sci, Fujian Coll, Fuzhou 350002, Peoples R China
  • [ 32 ] [Kang, Longtian]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fuzhou 350002, Fujian, Peoples R China

Reprint 's Address:

  • [Kang, Longtian]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fuzhou 350002, Fujian, Peoples R China;;

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Related Keywords:

Source :

APPLIED SURFACE SCIENCE

ISSN: 0169-4332

Year: 2024

Volume: 663

6 . 3 0 0

JCR@2023

Cited Count:

WoS CC Cited Count: 8

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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