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author:

Li, Shen (Li, Shen.) [1] | Mo, Qiao-Ling (Mo, Qiao-Ling.) [2] | Xiao, Yang (Xiao, Yang.) [3] | Xiao, Fang -Xing (Xiao, Fang -Xing.) [4] (Scholars:肖方兴)

Indexed by:

Scopus SCIE

Abstract:

Cuprous oxide (Cu2O)-based photocathodes have been attracting enduring interest for green and sustain-able solar fuel production by solar-driven photoelectrochemical (PEC) water splitting and CO2 reduction reactions. Although Cu2O is featured by the theoretically outstanding photoactivity owing to the favor-able band-gap and appropriate band alignment, wide-spread utilization of Cu2O is largely hampered by its severe photo-corrosion and difficulty in charge transfer/separation modulation, hence rendering fabricating robust, stable and high-efficiency Cu2O-based photoelectrodes a continuously challenging issue. In this review, fundamentals of PEC reactions including water splitting and CO2 reduction are con-cisely elucidated, and then diverse strategies for constructing a large variety of quintessential Cu2O-based photocathodes are comprehensively summarized. Subsequently, predominant Cu2O-based photocath-odes currently being extensively explored in PEC water splitting and CO2 reduction reactions are specif-ically introduced. Finally, future perspective and outlook of Cu2O-based photocathodes in these two booming research fields are forecasted. Our review could provide enriched information on rational design and utilization of Cu2O-based photocathodes for solar fuel production.(c) 2022 Elsevier B.V. All rights reserved.

Keyword:

Cu2O PEC PhotocatalyticCO2 reduction Photocatalytic Water Splitting Photocathode

Community:

  • [ 1 ] [Li, Shen]Fuzhou Univ, Coll Mat Sci & Engn, New Campus, Minhou 350108, Fujian, Peoples R China
  • [ 2 ] [Mo, Qiao-Ling]Fuzhou Univ, Coll Mat Sci & Engn, New Campus, Minhou 350108, Fujian, Peoples R China
  • [ 3 ] [Xiao, Yang]Fuzhou Univ, Coll Mat Sci & Engn, New Campus, Minhou 350108, Fujian, Peoples R China
  • [ 4 ] [Xiao, Fang -Xing]Fuzhou Univ, Coll Mat Sci & Engn, New Campus, Minhou 350108, Fujian, Peoples R China
  • [ 5 ] [Xiao, Fang -Xing]Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350108, Fujian, Peoples R China

Reprint 's Address:

  • [Xiao, Fang -Xing]Fuzhou Univ, Coll Mat Sci & Engn, New Campus, Minhou 350108, Fujian, Peoples R China;;

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Source :

COORDINATION CHEMISTRY REVIEWS

ISSN: 0010-8545

Year: 2023

Volume: 477

2 0 . 3

JCR@2023

2 0 . 3 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:39

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 22

SCOPUS Cited Count: 18

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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