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Cuprous oxide (Cu2O)-based photocathodes have been attracting enduring interest for green and sustain-able solar fuel production by solar-driven photoelectrochemical (PEC) water splitting and CO2 reduction reactions. Although Cu2O is featured by the theoretically outstanding photoactivity owing to the favor-able band-gap and appropriate band alignment, wide-spread utilization of Cu2O is largely hampered by its severe photo-corrosion and difficulty in charge transfer/separation modulation, hence rendering fabricating robust, stable and high-efficiency Cu2O-based photoelectrodes a continuously challenging issue. In this review, fundamentals of PEC reactions including water splitting and CO2 reduction are con-cisely elucidated, and then diverse strategies for constructing a large variety of quintessential Cu2O-based photocathodes are comprehensively summarized. Subsequently, predominant Cu2O-based photocath-odes currently being extensively explored in PEC water splitting and CO2 reduction reactions are specif-ically introduced. Finally, future perspective and outlook of Cu2O-based photocathodes in these two booming research fields are forecasted. Our review could provide enriched information on rational design and utilization of Cu2O-based photocathodes for solar fuel production.(c) 2022 Elsevier B.V. All rights reserved.
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COORDINATION CHEMISTRY REVIEWS
ISSN: 0010-8545
Year: 2023
Volume: 477
2 0 . 3
JCR@2023
2 0 . 3 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:39
JCR Journal Grade:1
CAS Journal Grade:1
Cited Count:
WoS CC Cited Count: 22
SCOPUS Cited Count: 18
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
Affiliated Colleges: