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author:

Yu, Fangyuan (Yu, Fangyuan.) [1] | Lin, Qifa (Lin, Qifa.) [2] | Zeng, Xiangfu (Zeng, Xiangfu.) [3] | Zhou, Ping (Zhou, Ping.) [4] | Wu, Xiao (Wu, Xiao.) [5] (Scholars:吴啸) | Lin, Cong (Lin, Cong.) [6] (Scholars:林枞) | Zhao, Chunlin (Zhao, Chunlin.) [7] (Scholars:赵纯林) | Gao, Min (Gao, Min.) [8] (Scholars:高旻) | Lin, Tengfei (Lin, Tengfei.) [9] (Scholars:林腾飞) | Jiang, Xingan (Jiang, Xingan.) [10] | Luo, Laihui (Luo, Laihui.) [11] | Zhang, Qiwei (Zhang, Qiwei.) [12]

Indexed by:

EI Scopus SCIE

Abstract:

High-quality (K0.5Na0.5)NbO3 (KNN)-based transparent ceramics are ideal candidates for 3D optical information storage and information anti-counterfeiting encryption. However, conventional single-mode storage and convenient replicability hinder their practical application. Here, by introducing Er3+ and Sr2+ into a KNN matrix, xSr-1Er-KNN translucent ceramics were prepared, and reversible modulations of ceramic colors, transmittances, down-shifting photoluminescence (DSPL) and up-conversion photoluminescence (UCPL) were achieved. At room temperature, the photochromic (PC) behavior induced high modulation contrasts of both 88% for dual-mode DSPL and UCPL under the excitations of 485 and 980 nm, respectively, exhibiting excellent multi-optical information storage. Moreover, the xSr-1Er-KNN ceramics showed conspicuous low-temperature optical temperature sensing performance through fluorescence intensity ratio technology (a maximum relative sensitivity of 0.023 K-1 was obtained at 213 K). The Er3+ and Sr2+ codoping in KNN not only improved the transmittance but also enriched intermediate trap levels to significantly increase the number of color centers, and improve the PC contrast and modulation degrees of both the DSPL and UCPL intensities. The potential applications of the xSr-1Er-KNN ceramics at distinct temperatures based on their diverse optical behaviors can guide the development of other optical multifunctional materials and devices.

Keyword:

Community:

  • [ 1 ] [Yu, Fangyuan]Fuzhou Univ, Dept Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 2 ] [Lin, Qifa]Fuzhou Univ, Dept Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 3 ] [Zeng, Xiangfu]Fuzhou Univ, Dept Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 4 ] [Zhou, Ping]Fuzhou Univ, Dept Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 5 ] [Wu, Xiao]Fuzhou Univ, Dept Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 6 ] [Lin, Cong]Fuzhou Univ, Dept Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 7 ] [Zhao, Chunlin]Fuzhou Univ, Dept Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 8 ] [Gao, Min]Fuzhou Univ, Dept Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 9 ] [Lin, Tengfei]Fuzhou Univ, Dept Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 10 ] [Jiang, Xingan]Ningbo Univ Technol, Inst Micro Nano Mat & Devices, Ningbo 315211, Peoples R China
  • [ 11 ] [Luo, Laihui]Ningbo Univ, Dept Microelect Sci & Engn, Ningbo 315211, Peoples R China
  • [ 12 ] [Zhang, Qiwei]Guangxi Normal Univ, Coll Phys & Technol, Guilin 541004, Peoples R China

Reprint 's Address:

  • [Wu, Xiao]Fuzhou Univ, Dept Mat Sci & Engn, Fuzhou 350108, Peoples R China;;

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Source :

INORGANIC CHEMISTRY FRONTIERS

ISSN: 2052-1553

Year: 2024

Issue: 22

Volume: 11

Page: 8025-8036

6 . 1 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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