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author:

Zheng, Xingke (Zheng, Xingke.) [1] | Du, Aochen (Du, Aochen.) [2] | Ye, Yun (Ye, Yun.) [3] | Chen, Enguo (Chen, Enguo.) [4] | Xu, Sheng (Xu, Sheng.) [5] | Guo, Tailiang (Guo, Tailiang.) [6]

Indexed by:

SCIE

Abstract:

Oxide of tungstate has consistently been pursued for use in optoelectronic applications. This study details the synthesis of AWO4 (A = Ba, Sr and Ca) using a high-temperature solid-state method. Additionally, theoretical calculations highlight its electronic structure, density of states, photoelectric properties, and vibrational modes. The x-ray diffraction of AWO4 (A = Ba, Sr and Ca) was meticulously introduced by the utilization of Rietveld for refinement. The refined lattice parameters substantially verified AWO4 (A = Ba, Sr and Ca) as a tetragonal system of scheelite with the spatial group of I41/a, and demonstrated significant alteration with the discrepancy in the radius of alkaline earth metal (A-site) ions. The electronic configuration and optical attributes of AWO4 (A = Ba, Sr and Ca) possessing scheelite-like structure were explored using density functional theory (DFT) based computational techniques. The theoretical blueprint was derived by optimizing the structure based on defects. The postulated optical bandgap energy confirms the occurrence of direct electronic transitions at Brillouin region G points. Calculations suggested the direct band gaps of BaWO4, SrWO4, and CaWO4 at 4.385, 3.123 and 3.813 eV. This was attributed to the energy levels produced by O and A-site atoms in the valence band, and W and O atoms in the conduction band. An examination of the polarization effect and uneven electronic charge distribution between [CaO8]6- and [WO4]2- clusters brought about by structural defects in AWO4 (A = Ba, Sr and Ca) was performed. Moreover, advanced investigations have been conducted on the elastic constants and mechanical durability of AWO4 (A = Ba, Sr and Ca). This research extensively calculated the elastic moduli of various matrices utilizing DFT. The critical Pugh's ratio value was found to be >1.75, it indicated that AWO4 (A = Ba, Sr and Ca) has significant potential as a resilient material.

Keyword:

DFT calculations electronic structure optical properties scheelite

Community:

  • [ 1 ] [Zheng, Xingke]Fuzhou Univ, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China
  • [ 2 ] [Du, Aochen]Fuzhou Univ, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China
  • [ 3 ] [Ye, Yun]Fuzhou Univ, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China
  • [ 4 ] [Chen, Enguo]Fuzhou Univ, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China
  • [ 5 ] [Xu, Sheng]Fuzhou Univ, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China
  • [ 6 ] [Guo, Tailiang]Fuzhou Univ, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China
  • [ 7 ] [Zheng, Xingke]Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350108, Peoples R China
  • [ 8 ] [Du, Aochen]Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350108, Peoples R China
  • [ 9 ] [Ye, Yun]Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350108, Peoples R China
  • [ 10 ] [Chen, Enguo]Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350108, Peoples R China
  • [ 11 ] [Xu, Sheng]Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350108, Peoples R China
  • [ 12 ] [Guo, Tailiang]Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350108, Peoples R China
  • [ 13 ] [Du, Aochen]Yili Normal Univ, Coll Phys Sci & Technol, Xinjiang Lab Phase Transit & Microstruct Condensed, Yining 835000, Peoples R China

Reprint 's Address:

  • [Du, Aochen]Fuzhou Univ, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China;;[Ye, Yun]Fuzhou Univ, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China;;[Du, Aochen]Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350108, Peoples R China;;[Ye, Yun]Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350108, Peoples R China;;[Du, Aochen]Yili Normal Univ, Coll Phys Sci & Technol, Xinjiang Lab Phase Transit & Microstruct Condensed, Yining 835000, Peoples R China;;

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Source :

PHYSICA SCRIPTA

ISSN: 0031-8949

Year: 2024

Issue: 7

Volume: 99

2 . 6 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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