Achieving　high　catalytic　activity　with　a　minimum　amount　of　platinum　(Pt)　is　crucial　for　accelerating　the　cathodic　hydrogen　evolution　reaction　(HER)　in　proton　exchange　membrane　(PEM)　water　electrolysis,　yet　it　remains　a　significant　challenge.　Herein,　a　directed　dual‐charge　pumping　strategy　to　tune　the　d‐orbital　electronic　distribution　of　Pt　nanoclusters　for　efficient　HER　catalysis　is　proposed.　Theoretical　analysis　reveals　that　the　ligand　effect　and　electronic　metal‐support　interactions　(EMSI)　create　an　effective　directional　electron　transfer　channel　for　the　d‐orbital　electrons　of　Pt,　which　in　turn　optimizes　the　binding　strength　to　H*,　thereby　significantly　enhancing　HER　efficiency　of　the　Pt　site.　Experimentally,　this　directed　dual‐charge　pumping　strategy　is　validated　by　elaborating　Sb‐doped　SnO2　(ATO)　supported　Fe‐doped　PtSn　heterostructure　catalysts　(Fe‐PtSn/ATO).　The　synthesized　3%Fe‐PtSn/ATO　catalysts　exhibit　lower　overpotential　(requiring　only　10.5 mV　to　reach　a　current　density　of　10 mA cm−2),　higher　mass　activity　(28.6　times　higher　than　commercial　20 wt.%　Pt/C),　and　stability　in　the　HER　process　in　acidic　media.　This　innovative　strategy　presents　a　promising　pathway　for　the　development　of　highly　efficient　HER　catalysts　with　low　Pt　loading.