Phenol　is　one　of　the　major　hazardous　organic　compounds　in　industrial　wastewater.　In　this　work,　a　highly　active　Pt/TiO2　catalyst　for　catalytic　wet　air　oxidation　(CWAO)　of　phenol　was　obtained　by　supporting　pre-synthesized　Pt　on　TiO2.　During　the　followed　hydrogen　reduction,　strong　hydrogen　spillover　occurred　without　the　migration　of　TiO2　onto　Pt.　The　reduced　support　then　enhanced　the　electron　transfer　from　TiO2　to　Pt,　increasing　the　percentage　of　partially　negative　Pt　(Pt　delta-),　which　has　been　confirmed　by　XPS.　The　strong　EMSI　made　the　obtained　catalyst　far　more　active　than　Pt/TiO2　prepared　by　impregnation　method.　The　electron-enriched　Pt/TiO2　achieved　total　organic　carbon　(TOC)　conversion　of　88.8%　and　TOF　149h(-1)　at　100　degrees　C　and　2　MPa　O-2,　while　conventional　Pt/TiO2　gave　TOC　conversion　of　39.5%　and　TOF　41　h(-1)-　for　CWAO　of　phenol.　Our　work　indicates　that　the　enhancement　of　EMSI　between　metal　and　support　can　be　an　effective　approach　to　develop　highly　active　catalysts　for　phenol　treatment.