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Hard carbon anodes (HCAs) possessing exceptional sodium storage properties undoubtedly represents one of the optimal choices for practicable sodium-ion batteries (SIBs). In further improving and optimizing the performance of SIBs, a systematic investigation of HCA structures in particular the microstructures of solid electrolyte interface (SEI) formed on the HCA surface and the sodium storage models is definitely needed. In this paper, the recent research progress in SIBs hard carbon anodes, the formed SEIs, the degradation mechanisms and the mitigation strategies for reducing degradation is comprehensively reviewed from three primary aspects: (1) the fundamental understanding of the sodium storage mechanisms of hard carbon in terms of the distinct modes including sodium adsorption/insertion, and pore filling within hard carbon materials; (2) based on the design, synthesis, theoretical characterization and performance optimization of new materials, the understanding of the structure-performance relationship of hard carbon anodes provides a potential approach for the design of high-performance SIBs anodes; and (3) the challenges related to the degradation of hard carbon anode and the formed SEI between its surface, and the mitigation strategies for reducing the degradation. It is anticipated that this review could provide valuable guidance for future research endeavors and commercial development related to hard carbon anodes for SIBs. © 2024 Elsevier Ltd
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Nano Energy
ISSN: 2211-2855
Year: 2024
Volume: 128
1 6 . 8 0 0
JCR@2023
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