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author:

Zhu, Kai-Qi (Zhu, Kai-Qi.) [1] | Ding, Quan (Ding, Quan.) [2] | Xu, Jiang-Hai (Xu, Jiang-Hai.) [3] | Yang, Yan-Ru (Yang, Yan-Ru.) [4] | Yang, Chen (Yang, Chen.) [5] (Scholars:杨臣) | Zhang, Jing (Zhang, Jing.) [6] | Zhang, Yan (Zhang, Yan.) [7] | Huang, Tai-Ming (Huang, Tai-Ming.) [8] | Yan, Wei-Mon (Yan, Wei-Mon.) [9] | Wan, Zhong-Min (Wan, Zhong-Min.) [10] | Wang, Xiao-Dong (Wang, Xiao-Dong.) [11]

Indexed by:

EI Scopus SCIE

Abstract:

This work proposes a design principle of the optimal thickness for cathode gas diffusion layers (GDLs) of proton exchange membrane fuel cells (PEMFCs) based on a balance of cell performances under both steady-state and load-varying conditions. Using a three-dimensional and two-phase model, the effects of cathode GDL thickness (50, 100, 200, and 400 mu m) on steady-state performances and transient response characteristics are studied. The results show that under steady-state conditions, an extremely thin cathode GDL would lead to non-uniform oxygen and liquid water distributions, whereas an especially thick cathode GDL would increase oxygen transport resistance. Thus, there is an optimal cathode GDL thickness, yielding the best steady-state performance. A current overshoot phenomenon, arising from high local oxygen concentrations at cathode catalyst layers (CLs), is observed when the load voltage decreases abruptly. Thinner cathode GDLs would weaken the overshoot and shorten the recovery time of current density. Conversely, low local oxygen concentrations at cathode CLs caused by high liquid water saturation levels lead to a current undershoot phenomenon when the load voltage increases abruptly. Thinner cathode GDLs would strengthen the undershoot but shorten the recovery time of current density. The optimal choice of cathode GDL thickness should weigh up the steady-state and the transient performance. Based on this principle, the optimal cathode GDL thickness is selected as 100 mu m.

Keyword:

Overshoot Proton exchange membrane fuel cell Response time Thickness of gas diffusion layer Undershoot

Community:

  • [ 1 ] [Zhu, Kai-Qi]North China Elect Power Univ, State Key Lab Alternate Elect Power Syst Renewabl, Beijing 102206, Peoples R China
  • [ 2 ] [Ding, Quan]North China Elect Power Univ, State Key Lab Alternate Elect Power Syst Renewabl, Beijing 102206, Peoples R China
  • [ 3 ] [Xu, Jiang-Hai]North China Elect Power Univ, State Key Lab Alternate Elect Power Syst Renewabl, Beijing 102206, Peoples R China
  • [ 4 ] [Yang, Yan-Ru]North China Elect Power Univ, State Key Lab Alternate Elect Power Syst Renewabl, Beijing 102206, Peoples R China
  • [ 5 ] [Wang, Xiao-Dong]North China Elect Power Univ, State Key Lab Alternate Elect Power Syst Renewabl, Beijing 102206, Peoples R China
  • [ 6 ] [Zhu, Kai-Qi]North China Elect Power Univ, Res Ctr Engn Thermophys, Beijing 102206, Peoples R China
  • [ 7 ] [Ding, Quan]North China Elect Power Univ, Res Ctr Engn Thermophys, Beijing 102206, Peoples R China
  • [ 8 ] [Xu, Jiang-Hai]North China Elect Power Univ, Res Ctr Engn Thermophys, Beijing 102206, Peoples R China
  • [ 9 ] [Yang, Yan-Ru]North China Elect Power Univ, Res Ctr Engn Thermophys, Beijing 102206, Peoples R China
  • [ 10 ] [Wang, Xiao-Dong]North China Elect Power Univ, Res Ctr Engn Thermophys, Beijing 102206, Peoples R China
  • [ 11 ] [Yang, Chen]Fuzhou Univ, Coll Chem Engn, Fuzhou 350116, Fujian, Peoples R China
  • [ 12 ] [Zhang, Jing]Hunan Inst Sci & Technol, Coll Mech Engn, Yueyang 414006, Hunan, Peoples R China
  • [ 13 ] [Zhang, Yan]Hunan Inst Sci & Technol, Coll Mech Engn, Yueyang 414006, Hunan, Peoples R China
  • [ 14 ] [Huang, Tai-Ming]Hunan Inst Sci & Technol, Coll Mech Engn, Yueyang 414006, Hunan, Peoples R China
  • [ 15 ] [Wan, Zhong-Min]Hunan Inst Sci & Technol, Coll Mech Engn, Yueyang 414006, Hunan, Peoples R China
  • [ 16 ] [Yan, Wei-Mon]Natl Taipei Univ Technol, Dept Energy & Refrigerating Air Conditioning Engn, Taipei 10608, Taiwan

Reprint 's Address:

  • [Wang, Xiao-Dong]North China Elect Power Univ, Res Ctr Engn Thermophys, Beijing 102206, Peoples R China;;[Wan, Zhong-Min]Hunan Inst Sci & Technol, Coll Mech Engn, Yueyang 414006, Hunan, Peoples R China

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Source :

ENERGY CONVERSION AND MANAGEMENT

ISSN: 0196-8904

Year: 2022

Volume: 267

1 0 . 4

JCR@2022

9 . 9 0 0

JCR@2023

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 19

SCOPUS Cited Count: 23

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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