P(V)-Promoted Rh-Catalyzed Highly Regioselective Hydroformylation of Styrenes under Mild Conditions - Details

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Abstract：

Hydroformylation　of　olefins　is　widely　used　in　the　chemical　industry　due　to　its　versatility　and　the　ability　to　produce　valuable　aldehydes　with　100%　atom　economy.　Herein,　a　hybrid　phosphate　promoter　was　found　to　efficiently　promote　rhodium-catalyzed　hydroformylation　of　styrenes　under　remarkably　mild　conditions　with　high　regioselectivities.　Preliminary　mechanistic　studies　revealed　that　the　weak　coordination　between　the　Rhodium　and　the　P=O　double　bond　of　this　pentavalent　phosphate　likely　induced　exceptional　reactivity　and　high　ratios　of　branched　aldehydes　to　linear　products.

Keyword：

branched selectivity hybrid phosphate hydroformylation styrene

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[ 1 ] [Ru T.]Department of Medicinal Chemistry, School of Pharmacy, Fudan University, 201203, Shanghai, China
[ 2 ] [Ru T.]Engineering Center of Catalysis and Synthesis for Chiral Molecules, Department of Chemistry, Fudan University, 200433, Shanghai, China
[ 3 ] [Ru T.]Shanghai Engineering Center of Industrial Asymmetric Catalysis for Chiral Drugs, 200433, Shanghai, China
[ 4 ] [Zhang Y.]Engineering Center of Catalysis and Synthesis for Chiral Molecules, Department of Chemistry, Fudan University, 200433, Shanghai, China
[ 5 ] [Zhang Y.]Shanghai Engineering Center of Industrial Asymmetric Catalysis for Chiral Drugs, 200433, Shanghai, China
[ 6 ] [Zhang Y.]College of Chemical Engineering, Fuzhou University, Fuzhou 350102, China
[ 7 ] [Wei Q.]Engineering Center of Catalysis and Synthesis for Chiral Molecules, Department of Chemistry, Fudan University, 200433, Shanghai, China
[ 8 ] [Wei Q.]Shanghai Engineering Center of Industrial Asymmetric Catalysis for Chiral Drugs, 200433, Shanghai, China
[ 9 ] [Wei Q.]College of Chemical Engineering, Fuzhou University, Fuzhou 350102, China
[ 10 ] [Zuo S.]Engineering Center of Catalysis and Synthesis for Chiral Molecules, Department of Chemistry, Fudan University, 200433, Shanghai, China
[ 11 ] [Zuo S.]Shanghai Engineering Center of Industrial Asymmetric Catalysis for Chiral Drugs, 200433, Shanghai, China
[ 12 ] [Jia Z.]Engineering Center of Catalysis and Synthesis for Chiral Molecules, Department of Chemistry, Fudan University, 200433, Shanghai, China
[ 13 ] [Jia Z.]Shanghai Engineering Center of Industrial Asymmetric Catalysis for Chiral Drugs, 200433, Shanghai, China
[ 14 ] [Chen F.-E.]Department of Medicinal Chemistry, School of Pharmacy, Fudan University, 201203, Shanghai, China
[ 15 ] [Chen F.-E.]Engineering Center of Catalysis and Synthesis for Chiral Molecules, Department of Chemistry, Fudan University, 200433, Shanghai, China
[ 16 ] [Chen F.-E.]Shanghai Engineering Center of Industrial Asymmetric Catalysis for Chiral Drugs, 200433, Shanghai, China
[ 17 ] [Chen F.-E.]College of Chemical Engineering, Fuzhou University, Fuzhou 350102, China

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Source ：

Molecules (Basel, Switzerland)

ISSN： 1420-3049

Year： 2024

Issue： 9

Volume： 29

3 . 0 6 0

JCR@2018

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ESI Highly Cited Papers on the List： 0 Unfold All

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30 Days PV： 1

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