P(V)-Promoted Rh-Catalyzed Highly Regioselective Hydroformylation of Styrenes under Mild Conditions - Details

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Abstract：

Hydroformylation　of　olefins　is　widely　used　in　the　chemical　industry　due　to　its　versatility　and　the　ability　to　produce　valuable　aldehydes　with　100%　atom　economy.　Herein,　a　hybrid　phosphate　promoter　was　found　to　efficiently　promote　rhodium-catalyzed　hydroformylation　of　styrenes　under　remarkably　mild　conditions　with　high　regioselectivities.　Preliminary　mechanistic　studies　revealed　that　the　weak　coordination　between　the　Rhodium　and　the　P=O　double　bond　of　this　pentavalent　phosphate　likely　induced　exceptional　reactivity　and　high　ratios　of　branched　aldehydes　to　linear　products.

Keyword：

branched selectivity hybrid phosphate hydroformylation styrene

Community：

[ 1 ] [Ru, Tong]Fudan Univ, Sch Pharm, Dept Med Chem, Shanghai 201203, Peoples R China
[ 2 ] [Chen, Fen-Er]Fudan Univ, Sch Pharm, Dept Med Chem, Shanghai 201203, Peoples R China
[ 3 ] [Ru, Tong]Fudan Univ, Engn Ctr Catalysis & Synth Chiral Mol, Dept Chem, Shanghai 200433, Peoples R China
[ 4 ] [Zhang, Yajiao]Fudan Univ, Engn Ctr Catalysis & Synth Chiral Mol, Dept Chem, Shanghai 200433, Peoples R China
[ 5 ] [Wei, Qiuxiang]Fudan Univ, Engn Ctr Catalysis & Synth Chiral Mol, Dept Chem, Shanghai 200433, Peoples R China
[ 6 ] [Zuo, Sheng]Fudan Univ, Engn Ctr Catalysis & Synth Chiral Mol, Dept Chem, Shanghai 200433, Peoples R China
[ 7 ] [Jia, Zhenhua]Fudan Univ, Engn Ctr Catalysis & Synth Chiral Mol, Dept Chem, Shanghai 200433, Peoples R China
[ 8 ] [Chen, Fen-Er]Fudan Univ, Engn Ctr Catalysis & Synth Chiral Mol, Dept Chem, Shanghai 200433, Peoples R China
[ 9 ] [Ru, Tong]Shanghai Engn Ctr Ind Asymmetr Catalysis Chiral Dr, Shanghai 200433, Peoples R China
[ 10 ] [Zhang, Yajiao]Shanghai Engn Ctr Ind Asymmetr Catalysis Chiral Dr, Shanghai 200433, Peoples R China
[ 11 ] [Wei, Qiuxiang]Shanghai Engn Ctr Ind Asymmetr Catalysis Chiral Dr, Shanghai 200433, Peoples R China
[ 12 ] [Zuo, Sheng]Shanghai Engn Ctr Ind Asymmetr Catalysis Chiral Dr, Shanghai 200433, Peoples R China
[ 13 ] [Jia, Zhenhua]Shanghai Engn Ctr Ind Asymmetr Catalysis Chiral Dr, Shanghai 200433, Peoples R China
[ 14 ] [Chen, Fen-Er]Shanghai Engn Ctr Ind Asymmetr Catalysis Chiral Dr, Shanghai 200433, Peoples R China
[ 15 ] [Zhang, Yajiao]Fuzhou Univ, Coll Chem Engn, Fuzhou 350102, Peoples R China
[ 16 ] [Wei, Qiuxiang]Fuzhou Univ, Coll Chem Engn, Fuzhou 350102, Peoples R China
[ 17 ] [Chen, Fen-Er]Fuzhou Univ, Coll Chem Engn, Fuzhou 350102, Peoples R China

Reprint 's Address：

陈芬儿
[Chen, Fen-Er]Fudan Univ, Sch Pharm, Dept Med Chem, Shanghai 201203, Peoples R China;;[Jia, Zhenhua]Fudan Univ, Engn Ctr Catalysis & Synth Chiral Mol, Dept Chem, Shanghai 200433, Peoples R China;;[Chen, Fen-Er]Fudan Univ, Engn Ctr Catalysis & Synth Chiral Mol, Dept Chem, Shanghai 200433, Peoples R China;;[Jia, Zhenhua]Shanghai Engn Ctr Ind Asymmetr Catalysis Chiral Dr, Shanghai 200433, Peoples R China;;[Chen, Fen-Er]Shanghai Engn Ctr Ind Asymmetr Catalysis Chiral Dr, Shanghai 200433, Peoples R China;;[Chen, Fen-Er]Fuzhou Univ, Coll Chem Engn, Fuzhou 350102, Peoples R China

Email：

19111030025@fudan.edu.cn |
200410027@fzu.edu.cn |
qiuxiangwei21@163.com |
zhenhua_jia@fudan.edu.cn |
rfchen@fudan.edu.cn

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