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author:

Al-Abbasi, Malek (Al-Abbasi, Malek.) [1] | Zhao, Yanrui (Zhao, Yanrui.) [2] | He, Honggang (He, Honggang.) [3] | Liu, Hui (Liu, Hui.) [4] | Xia, Huarong (Xia, Huarong.) [5] | Zhu, Tianxue (Zhu, Tianxue.) [6] | Wang, Kexuan (Wang, Kexuan.) [7] | Xu, Zhu (Xu, Zhu.) [8] | Wang, Huibo (Wang, Huibo.) [9] | Zhang, Wei (Zhang, Wei.) [10] | Lai, Yuekun (Lai, Yuekun.) [11] (Scholars:赖跃坤) | Ge, Mingzheng (Ge, Mingzheng.) [12]

Indexed by:

ESCI

Abstract:

Over the past decades, there has been a growing interest in rechargeable aqueous Zn-ion batteries (AZIBs) as a viable substitute for lithium-ion batteries. This is primarily due to their low cost, lower redox potential, and high safety. Nevertheless, the progress of Zn metal anodes has been impeded by various challenges, including the growth of dendrites, corrosion, and hydrogen evolution reaction during repeated cycles that result in low Coulombic efficiency and a short lifetime. Therefore, we represent recent advances in Zn metal anode protection for constructing high-performance AZIBs. Besides, we show in-depth analyses and supposed hypotheses on the working mechanism of these issues associated with mildly acidic aqueous electrolytes. Meanwhile, design principles and feasible strategies are proposed to suppress dendrites' formation of Zn batteries, including electrode design, electrolyte modification, and interface regulation, which are suitable for restraining corrosion and hydrogen evolution reaction. Finally, the current challenges and future trends are raised to pave the way for the commercialization of AZIBs. These design principles and potential strategies are applicable in other metal-ion batteries, such as Li and K metal batteries. State-of-the-art advances in the rational design of aqueous zinc-ion batteries and their progress in practical applications are systematically summarized in this review. Various strategies to protect the Zn anode from forming dendrites' formation, restricting hydrogen production and corrosion, are proposed from both working mechanism and material perspectives, including structure design, electrolyte modification, and interface regulation. image

Keyword:

aqueous Zn-ion batteries dendrites formation electrolyte modification interface regulation structure design

Community:

  • [ 1 ] [Al-Abbasi, Malek]Nantong Univ, Sch Text & Clothing, Nantong 226019, Peoples R China
  • [ 2 ] [Zhao, Yanrui]Nantong Univ, Sch Text & Clothing, Nantong 226019, Peoples R China
  • [ 3 ] [He, Honggang]Nantong Univ, Sch Text & Clothing, Nantong 226019, Peoples R China
  • [ 4 ] [Liu, Hui]Nantong Univ, Sch Text & Clothing, Nantong 226019, Peoples R China
  • [ 5 ] [Zhang, Wei]Nantong Univ, Sch Text & Clothing, Nantong 226019, Peoples R China
  • [ 6 ] [Ge, Mingzheng]Nantong Univ, Sch Text & Clothing, Nantong 226019, Peoples R China
  • [ 7 ] [Xia, Huarong]Nanyang Technol Univ, Innovat Ctr Flexible Devices iFLEX, Max Planck NTU Joint Lab Artificial Senses, Singapore, Singapore
  • [ 8 ] [Zhu, Tianxue]Fuzhou Univ, Coll Chem Engn, Fuzhou, Peoples R China
  • [ 9 ] [Wang, Huibo]Fuzhou Univ, Coll Chem Engn, Fuzhou, Peoples R China
  • [ 10 ] [Lai, Yuekun]Fuzhou Univ, Coll Chem Engn, Fuzhou, Peoples R China
  • [ 11 ] [Wang, Kexuan]Univ Macau, Inst Appl Phys & Mat Engn, Taipa, Macau, Peoples R China
  • [ 12 ] [Xu, Zhu]Univ Macau, Inst Appl Phys & Mat Engn, Taipa, Macau, Peoples R China
  • [ 13 ] [Ge, Mingzheng]Soochow Univ, Key Lab Jiangsu Prov Silk Engn, Suzhou, Peoples R China

Reprint 's Address:

  • [Liu, Hui]Nantong Univ, Sch Text & Clothing, Nantong 226019, Peoples R China;;[Zhang, Wei]Nantong Univ, Sch Text & Clothing, Nantong 226019, Peoples R China;;[Ge, Mingzheng]Nantong Univ, Sch Text & Clothing, Nantong 226019, Peoples R China

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Source :

CARBON NEUTRALIZATION

ISSN: 2769-3333

Year: 2024

Issue: 1

Volume: 3

Page: 108-141

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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