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author:

Xu, Zhu (Xu, Zhu.) [1] | Wang, Kexuan (Wang, Kexuan.) [2] | Li, Heng (Li, Heng.) [3] | Wang, Huibo (Wang, Huibo.) [4] | Ge, Mingzheng (Ge, Mingzheng.) [5] | Zhang, Yanyan (Zhang, Yanyan.) [6] (Scholars:张焱焱) | Tang, Yuxin (Tang, Yuxin.) [7] (Scholars:汤育欣) | Chen, Shi (Chen, Shi.) [8]

Indexed by:

EI Scopus SCIE

Abstract:

Rechargeable metal batteries have received widespread attention due to their high energy density by using pure metal as the anode. However, there are still many fundamental problems that need to be solved before approaching practical applications. The critical ones are low charge/discharge current due to slow ion transport, short cycle lifetime due to poor anode/cathode stability, and unsatisfied battery safety. To tackle these problems, various strategies have been suggested. Among them, electrolyte additive is one of the most widely used strategies. Most of the additives currently studied are soluble, but their reliability is questionable, and they can easily affect the electrochemical process, causing unwanted battery performance decline. On the contrary, insoluble additives with excellent chemical stability, high mechanical strength, and dimensional tunability have attracted considerable research exploration recently. However, there is no timely review on insoluble additives in metal batteries yet. This review summarizes various functions of insoluble additives: ion transport modulation, metal anode protection, cathode amelioration, as well as battery safety enhancement. Future research directions and challenges for insoluble solid additives are also proposed. It is expected this review will stimulate inspiration and arouse extensive studies on further improvement in the overall performance of metal batteries. Highly stable insoluble additives in metal batteries provide a feasible approach to counteract additive depletion as well as its accompanying side reactions. This review summarizes recent advances in insoluble additives for metal batteries with a unique focus on the following aspects: modulation of ion transport, protection of metal anodes, amelioration of cathodes, and enhancement of battery safety. image

Keyword:

battery safety electrode stability insoluble additives ion transport metal batteries

Community:

  • [ 1 ] [Xu, Zhu]Univ Macau, Inst Appl Phys & Mat Engn, Macau 999078, Peoples R China
  • [ 2 ] [Wang, Kexuan]Univ Macau, Inst Appl Phys & Mat Engn, Macau 999078, Peoples R China
  • [ 3 ] [Li, Heng]Univ Macau, Inst Appl Phys & Mat Engn, Macau 999078, Peoples R China
  • [ 4 ] [Wang, Huibo]Univ Macau, Inst Appl Phys & Mat Engn, Macau 999078, Peoples R China
  • [ 5 ] [Ge, Mingzheng]Univ Macau, Inst Appl Phys & Mat Engn, Macau 999078, Peoples R China
  • [ 6 ] [Chen, Shi]Univ Macau, Inst Appl Phys & Mat Engn, Macau 999078, Peoples R China
  • [ 7 ] [Li, Heng]Shanghai Inst Ceram, Chinese Acad Sci, State Key Lab High Performance Ceram & Superfine M, Shanghai 200050, Peoples R China
  • [ 8 ] [Zhang, Yanyan]Fuzhou Univ, Coll Chem Engn, Fuzhou 350116, Peoples R China
  • [ 9 ] [Tang, Yuxin]Fuzhou Univ, Coll Chem Engn, Fuzhou 350116, Peoples R China

Reprint 's Address:

  • 汤育欣

    [Li, Heng]Univ Macau, Inst Appl Phys & Mat Engn, Macau 999078, Peoples R China;;[Chen, Shi]Univ Macau, Inst Appl Phys & Mat Engn, Macau 999078, Peoples R China;;[Li, Heng]Shanghai Inst Ceram, Chinese Acad Sci, State Key Lab High Performance Ceram & Superfine M, Shanghai 200050, Peoples R China;;[Tang, Yuxin]Fuzhou Univ, Coll Chem Engn, Fuzhou 350116, Peoples R China

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ISSN: 1613-6810

Year: 2024

Issue: 37

Volume: 20

1 3 . 0 0 0

JCR@2023

Cited Count:

WoS CC Cited Count: 8

SCOPUS Cited Count: 3

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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