Metal-free semiconductors for visible-light-induced carbocarboxylation of styrenes with aliphatic redox-active esters and CO2 - Details

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Abstract：

A　sustainable　system　for　the　carbocarboxylation　of　olefins　with　redox-active　esters　and　CO2via　visible-light-induced　photoredox　catalysis　has　been　developed　using　metal-free　boron　carbonitride　(BCN)　as　the　photocatalyst.　The　scheme　introduces　versatile　alkyl　groups　(including　primary,　secondary,　and　tertiary)　and　CO2　into　the　C-C　double　bond　in　a　fully　regioselective　manner　to　produce　valuable　carboxylic　derivatives　with　excellent　yields.　©　2024　The　Royal　Society　of　Chemistry.

Keyword：

Carbon dioxide Carbon nitride Esters Redox reactions Styrene

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[ 1 ] [Hou, Hao]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou; 350116, China
[ 2 ] [Luo, Meizhen]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou; 350116, China
[ 3 ] [Zhai, Senmao]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou; 350116, China
[ 4 ] [Yuan, Tao]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou; 350116, China
[ 5 ] [Yuan, Tao]College of Chemical Engineering, Fuzhou University, Fuzhou; 350116, China
[ 6 ] [Zheng, Meifang]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou; 350116, China
[ 7 ] [Wang, Sibo]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou; 350116, China

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Source ：

Green Chemistry

ISSN： 1463-9262

Year： 2023

Issue： 3

Volume： 26

Page： 1317-1321

9 . 3

JCR@2023

9 . 3 0 0

JCR@2023

JCR Journal Grade：1

CAS Journal Grade：2

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WoS CC Cited Count：

SCOPUS Cited Count： 15

ESI Highly Cited Papers on the List： 0 Unfold All

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30 Days PV： 0

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