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[期刊论文]

Fast Energy Storage of SnS2 Anode Nanoconfined in Hollow Porous Carbon Nanofibers for Lithium-Ion Batteries

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author:

Liang, Fanghua (Liang, Fanghua.) [1] | Dong, Huilong (Dong, Huilong.) [2] | Dai, Jiamu (Dai, Jiamu.) [3] | Unfold

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EI

Abstract:

The development of conversion-typed anodes with ultrafast charging and large energy storage is quite challenging due to the sluggish ions/electrons transfer kinetics in bulk materials and fracture of the active materials. Herein, the design of porous carbon nanofibers/SnS2 composite (SnS2@N-HPCNFs) for high-rate energy storage, where the ultrathin SnS2 nanosheets are nanoconfined in N-doped carbon nanofibers with tunable void spaces, is reported. The highly interconnected carbon nanofibers in three-dimensional (3D) architecture provide a fast electron transfer pathway and alleviate the volume expansion of SnS2, while their hierarchical porous structure facilitates rapid ion diffusion. Specifically, the anode delivers a remarkable specific capacity of 1935.50 mAh g−1 at 0.1 C and excellent rate capability up to 30 C with a specific capacity of 289.60 mAh g−1. Meanwhile, at a high rate of 20 C, the electrode displays a high capacity retention of 84% after 3000 cycles and a long cycle life of 10 000 cycles. This work provides a deep insight into the construction of electrodes with high ionic/electronic conductivity for fast-charging energy storage devices. © 2023 The Authors. Advanced Science published by Wiley-VCH GmbH.

Keyword:

Anodes Carbon nanofibers Charging (batteries) Doping (additives) Energy storage Ions IV-VI semiconductors Lithium-ion batteries Nanosheets Porous materials Semiconducting tin compounds Storage (materials) Sulfur compounds

Community:

  • [ 1 ] [Liang, Fanghua]School of Textile & Clothing, Nantong University, Nantong; 226019, China
  • [ 2 ] [Liang, Fanghua]Faculty of Textile Science and Technology, Shinshu University, Tokida 3-15-1, Nagano, Ueda; 386-8567, Japan
  • [ 3 ] [Dong, Huilong]School of Materials Engineering, Changshu Institute of Technology, Changshu; 215500, China
  • [ 4 ] [Dai, Jiamu]School of Textile & Clothing, Nantong University, Nantong; 226019, China
  • [ 5 ] [He, Honggang]School of Textile & Clothing, Nantong University, Nantong; 226019, China
  • [ 6 ] [Zhang, Wei]School of Textile & Clothing, Nantong University, Nantong; 226019, China
  • [ 7 ] [Chen, Shi]Institute of Applied Physics and Materials Engineering, University of Macau, 999078, China
  • [ 8 ] [Lv, Dong]Department of Biomedical Sciences, City University of Hong Kong, 999077, Hong Kong
  • [ 9 ] [Liu, Hui]School of Textile & Clothing, Nantong University, Nantong; 226019, China
  • [ 10 ] [Kim, Ick Soo]Faculty of Textile Science and Technology, Shinshu University, Tokida 3-15-1, Nagano, Ueda; 386-8567, Japan
  • [ 11 ] [Lai, Yuekun]College of Chemical Engineering, Fuzhou University, Fuzhou; 350116, China
  • [ 12 ] [Tang, Yuxin]College of Chemical Engineering, Fuzhou University, Fuzhou; 350116, China
  • [ 13 ] [Ge, Mingzheng]School of Textile & Clothing, Nantong University, Nantong; 226019, China
  • [ 14 ] [Ge, Mingzheng]Institute of Applied Physics and Materials Engineering, University of Macau, 999078, China

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Source :

Advanced Science

Year: 2024

Issue: 4

Volume: 11

1 4 . 3 0 0

JCR@2023

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 13

30 Days PV: 1

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Online/Total:50/10382008
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