author:
Liang, Fanghua
(Liang, Fanghua.)
[1]
|
Dong, Huilong
(Dong, Huilong.)
[2]
|
Dai, Jiamu
(Dai, Jiamu.)
[3]
|
He, Honggang
(He, Honggang.)
[4]
|
Zhang, Wei
(Zhang, Wei.)
[5]
|
Chen, Shi
(Chen, Shi.)
[6]
|
Lv, Dong
(Lv, Dong.)
[7]
|
Liu, Hui
(Liu, Hui.)
[8]
|
Kim, Ick Soo
(Kim, Ick Soo.)
[9]
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Lai, Yuekun
(Lai, Yuekun.)
[10]
|
Tang, Yuxin
(Tang, Yuxin.)
[11]
|
Ge, Mingzheng
(Ge, Mingzheng.)
[12]
Unfold
Abstract:
The development of conversion-typed anodes with ultrafast charging and large energy storage is quite challenging due to the sluggish ions/electrons transfer kinetics in bulk materials and fracture of the active materials. Herein, the design of porous carbon nanofibers/SnS2 composite (SnS2@N-HPCNFs) for high-rate energy storage, where the ultrathin SnS2 nanosheets are nanoconfined in N-doped carbon nanofibers with tunable void spaces, is reported. The highly interconnected carbon nanofibers in three-dimensional (3D) architecture provide a fast electron transfer pathway and alleviate the volume expansion of SnS2, while their hierarchical porous structure facilitates rapid ion diffusion. Specifically, the anode delivers a remarkable specific capacity of 1935.50 mAh g−1 at 0.1 C and excellent rate capability up to 30 C with a specific capacity of 289.60 mAh g−1. Meanwhile, at a high rate of 20 C, the electrode displays a high capacity retention of 84% after 3000 cycles and a long cycle life of 10 000 cycles. This work provides a deep insight into the construction of electrodes with high ionic/electronic conductivity for fast-charging energy storage devices. © 2023 The Authors. Advanced Science published by Wiley-VCH GmbH.
Keyword:
Anodes
Carbon nanofibers
Charging (batteries)
Doping (additives)
Energy storage
Ions
IV-VI semiconductors
Lithium-ion batteries
Nanosheets
Porous materials
Semiconducting tin compounds
Storage (materials)
Sulfur compounds
Classification
525.7 Energy Storage - 694.4 Storage - 702.1.2 Secondary Batteries - 712.1 Semiconducting Materials - 712.1.2 Compound Semiconducting Materials - 714.1 Electron Tubes - 761 Nanotechnology - 933 Solid State Physics - 951 Materials Science
Type
F.L., H.D., and J.D. contributed equally to this work. This work was supported by the National Natural Science Foundation of China (52202256), the Natural Science Foundation of Jiangsu Province of China (BK20220612), the Science and Technology Development Fund, Macao SAR (0096/2020/A2, 0013/2021/AMJ, and 0082/2022/A2), and the Opening Project of Key Laboratory of Jiangsu Province for Silk Engineering, Soochow University (KJS2277). The authors also acknowledge the funds from Jiangsu University Qinglan Project" and the Young Elite Scientists Sponsorship Program of Jiangsu Association for Science and Technology. The authors thank Nantong University Analysis and Testing Center for the technical support.F.L.
Access Number
EI:20234915151826