In　the　electrochemical　CO2　reduction　reaction　(CO2RR),　the　coverages　of　*CO　and　*H　intermediates　on　a　catalyst　surface　are　critical　for　the　selective　generation　of　C-1　or　C-2　products.　In　this　work,　we　have　synthesized　several　CuxZnyMnz　ternary　alloy　electrocatalysts,　including　Cu8ZnMn,　Cu8Zn6Mn,　and　Cu8ZnMn2,　by　varying　the　doping　compositions　of　Zn　and　Mn,　which　are　efficient　in　binding　*CO　and　*H　adsorbates　in　the　CO2　electroreduction　process,　respectively.　The　increase　of　*H　coverage　allows　to　promotion　of　the　CH4　and　H-2　formation,　while　the　increase　of　the　*CO　coverage　facilitates　the　production　of　C2H4　and　CO.　As　a　result,　the　Cu8ZnMn　catalyst　presented　a　high　CO2-to-CH4　partial　current　density　(-418　+/-　22　mA　cm(-2))　with　a　Faradaic　efficiency　of　55　+/-　2.8%,　while　the　Cu8Zn6Mn　catalyst　exhibited　a　CO2-to-C2H4　partial　current　density　(-440　+/-　41　mA　cm(-2))　with　a　Faradaic　efficiency　of　58　+/-　4.5%.　The　study　suggests　a　useful　strategy　for　rational　design　and　fabrication　of　Cu　electrocatalysts　with　different　doping　for　tailoring　the　reduction　products.