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Oil contamination and industrial organic pollutants emission have been a serious problem affecting the ecological and residential environment. Membrane-based separation shows great application prospect due to its low-cost, environmental-friendly and easy operation. Therefore, the development of efficient oil-water separation membranes is highly desirable. Herein, a fabric filter with superwettability was prepared by coating urchin-like fluorinated covalent organic frameworks (COFs) on fabric, which was well utilized in filtering immiscible oil-water mixture and surfactant-stabilized water-in-oil emulsion driven only by gravity for the first time. The as-prepared COF fabric filter (defined as fabric@u-FCOF) possessed many outstanding properties, including superhydrophobicity with the water contact angle of approximately 151.6 degrees, satisfactory resistance for alkaline, acidic and saline environments, as well as superior mechanical durability under harsh conditions. Because of the super-micropore of fabric@u-FCOF and the nanopore in the COF coating, the obtained fabric@u-FCOF exhibited excellent performances in terms of separation efficiency and permeability, in which the oil flux was up to 16964 L.m(-1).h(-2) and separation efficiency for the mixed o-dichlorobenzene/water was higher than 99.4%. In addition, the fabric@u-FCOF also showed excellent self-cleaning performance due to the micro/nano hierarchical structure of its surface. These excellent properties make it an ideal candidate for applications of oil/water separation and water purification.
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JOURNAL OF HAZARDOUS MATERIALS
ISSN: 0304-3894
Year: 2023
Volume: 459
1 2 . 2
JCR@2023
1 2 . 2 0 0
JCR@2023
JCR Journal Grade:1
CAS Journal Grade:1
Cited Count:
WoS CC Cited Count: 13
SCOPUS Cited Count: 15
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
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