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author:

Wang, Peng (Wang, Peng.) [1] | Liao, Huafei (Liao, Huafei.) [2] | Yang, Meng (Yang, Meng.) [3] | Wu, Lizhi (Wu, Lizhi.) [4] (Scholars:吴立志) | Tang, Yu (Tang, Yu.) [5] (Scholars:汤禹) | Tan, Li (Tan, Li.) [6] (Scholars:谭理)

Indexed by:

EI Scopus SCIE

Abstract:

The deactivation of Pt-based catalysts is the most critical problem in nonoxidative propane dehydrogenation reaction (PDH), usually manifested in carbon deposition and active site sintering. Zn, as another cheap metal with more abundant reserves than Sn, is also widely used as an assistant in Pt-based catalysts. However, both of them are easy to be reduced to metal valence state and lost in the reaction process. Herein, the enlarged quantities of Zn are applied in the bimetallic Pt-Zn catalyst preparation. As confirmed by the increased reduction temperature of oxidized Zn species, it effectively minimizes the influence of the active metal mobility caused by Zn loss. At the same time, the constructed bimetallic structure modulates the surface acidity of Zn species and presents benign propylene desorption ability, thus the formed highly dispersed Pt sites on the surface of Pt1Zn1 alloy are well-matched with its high propylene selectivity (similar to 98.6%). In addition, the rich-ZnPt(1)Zn(1)sites are beneficial for enhancing the capability of resisting-coke, thus retarding the deactivation of this catalyst.

Keyword:

Alloy particles Anti-coking High propylene selectivity Pt active sites Rich-Zn

Community:

  • [ 1 ] [Wang, Peng]Fuzhou Univ, Inst Mol Catalysis & In Situ Operando Studies, Coll Chem, Fuzhou 350108, Peoples R China
  • [ 2 ] [Liao, Huafei]Fuzhou Univ, Inst Mol Catalysis & In Situ Operando Studies, Coll Chem, Fuzhou 350108, Peoples R China
  • [ 3 ] [Yang, Meng]Fuzhou Univ, Inst Mol Catalysis & In Situ Operando Studies, Coll Chem, Fuzhou 350108, Peoples R China
  • [ 4 ] [Wu, Lizhi]Fuzhou Univ, Inst Mol Catalysis & In Situ Operando Studies, Coll Chem, Fuzhou 350108, Peoples R China
  • [ 5 ] [Tang, Yu]Fuzhou Univ, Inst Mol Catalysis & In Situ Operando Studies, Coll Chem, Fuzhou 350108, Peoples R China
  • [ 6 ] [Tan, Li]Fuzhou Univ, Inst Mol Catalysis & In Situ Operando Studies, Coll Chem, Fuzhou 350108, Peoples R China

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Source :

FUEL

ISSN: 0016-2361

Year: 2023

Volume: 354

6 . 7

JCR@2023

6 . 7 0 0

JCR@2023

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 4

SCOPUS Cited Count: 8

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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