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author:

Li, X. (Li, X..) [1] | Cai, J. (Cai, J..) [2] | Li, M. (Li, M..) [3] | Zhang, L. (Zhang, L..) [4] | Chen, Z. (Chen, Z..) [5]

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Scopus

Abstract:

Integrated membranes with filtration and photocatalytic functions have been considered as an effective strategy for purifying flowing wastewater, but the design and preparation of high-efficiency and low-cost membranes is still of great urgency. Herein, we report efficient recyclable BiOBrxI1-x fibrous filter membranous photocatalyst prepared through the in-situ growth of BiOBrxI1-x solid-solutions with tunable band-gaps on carbon fiber cloth (CFC). The fabrication was performed via a facile dipping-solvothermal synthesis of BiOBrxI1-x solid-solutions nanoplates on CFC with different I/Br ratios in the precursor solution. With the increase of I/Br ratio from 0 to 4, CFC/BiOBrxI1-x solid-solutions exhibit a re-shifted in the photoabsorption edge from 420 to 620 nm, leading to the tuning of the band-gap from 2.49 to 1.81 eV. Under visible light illumination for 120 min, CFC/BiOBrxI1-x solid-solutions have the tuned photocatalytic activity, where CFC/BiOBr0.8I0.2 shows the highest degradation efficiency toward various antibiotics (such as levofloxacin (LVFX, 94.1%), ciprofloxacin (CIP, 94.5%), and tetracycline (TC, 98.9%)) as well as dyes (such as acid orange 7 (AO7, 91.4%). Especially, when CFC/BiOBr0.8I0.2 is used as a flexible membrane to a construct multi-grade unit for treating the flowing sewage, the degradation efficiency of LVFX goes up from 3.9% in the first grade to 96.2% in the tenth grade. Therefore, the present CFC/BiOBr0.8I0.2 not only possesses great potential as a flexible membrane-shaped photocatalyst for purifying the flowing sewage efficiently but also provides some insights for developing new types of purifying membranes and devices. © 2023 Elsevier Ltd

Keyword:

BiOBrxI1-x solid-solution Carbon fiber cloth Filtration membrane Flowing wastewater Photocatalysis

Community:

  • [ 1 ] [Li X.]Department of Interventional and Vascular Surgery, Shanghai Tenth People's Hospital, Tongji University School of Medicine, Shanghai, 200072, China
  • [ 2 ] [Li X.]State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Environmental Science and Engineering, Donghua University, Shanghai, 201620, China
  • [ 3 ] [Cai J.]State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Environmental Science and Engineering, Donghua University, Shanghai, 201620, China
  • [ 4 ] [Cai J.]State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou, 350116, China
  • [ 5 ] [Li M.]Department of Interventional and Vascular Surgery, Shanghai Tenth People's Hospital, Tongji University School of Medicine, Shanghai, 200072, China
  • [ 6 ] [Zhang L.]State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Environmental Science and Engineering, Donghua University, Shanghai, 201620, China
  • [ 7 ] [Zhang L.]State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou, 350116, China
  • [ 8 ] [Zhang L.]Shanghai Institute of Pollution Control and Ecological Security, Shanghai, 200092, China
  • [ 9 ] [Chen Z.]Department of Interventional and Vascular Surgery, Shanghai Tenth People's Hospital, Tongji University School of Medicine, Shanghai, 200072, China
  • [ 10 ] [Chen Z.]College of Materials Science and Engineering, Donghua University, Shanghai, 201620, China

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Source :

Journal of Cleaner Production

ISSN: 0959-6526

Year: 2023

Volume: 414

9 . 8

JCR@2023

9 . 8 0 0

JCR@2023

ESI HC Threshold:35

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 8

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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