Metal-organic　frameworks　(MOFs)　materials　featured　large　specific　surface　area,　unique　porous　structure　and　highly　crystalline　nature　which　rendered　them　ideal　catalysts　in　solar　light　conversion.　Generally,　the　catalytic　H-2　generation　activity　of　the　MOFs　was　rather　low　which　restricted　its　application.　The　effective　co-catalyst　introduction　could　enhance　its　overall　performance　via　reducing　the　overpotential　of　hydrogen　production　while　facili-tating　charges　transfer　and　increasing　reactive　sites.　Herein,　an　two-dimensional　(2D)　O,P-MoS2　nanosheets　cocatalyst　with　adequate　edge-S　active　sites　and　high　1T-phase　content　were　fabricated　via　co-doping　of　O　and　P　atoms.　Rational　coupling　the　2D　O,　P-MoS2　nanosheets　with　2D　NH2-MIL-125(Ti)　nanoplate　can　afford　greatly　improved　photocatalytic　H-2　production　rate　of　339.3　mmol　center　dot　g(-1)center　dot　h(-1),　which　was　11.6　and　6.7　times　of　pure　NH2-MIL-125(Ti)　and　NH2-MIL-125(Ti)/commercial　MoS2　composite,　respectively.　DFT　calculation　revealed　that　the　edge-S　serve　as　the　active　sites　for　H*　adsorption　rather　than　the　plane-S　and　O　sites　in　O,　P-MoS2　or　the　O　and　S　sites　in　O-MoS2.　Compared　with　the　commercial　MoS2　with　completely　2H-phase,　the　dual-doping　can　create　higher-density　unsaturated　edge-S　atoms　and　more　1T　phase　which　can　improve　the　reactivity　of　NH2-MIL-125(Ti)　via　inducing　the　breaking　of　Mo-S　bonds　and　providing　higher　electrical　conductivity.　Dual　non-metal　atom　doping　of　MoS2　cocatalyst　featured　abundant　edge-S　active　centers　and　high　concentration　of　1T-phase　offered　a　facile　and　effective　method　to　developing　highly　efficient　catalysts　toward　solar-energy　conversion.　(c)　2023　Hydrogen　Energy　Publications　LLC.　Published　by　Elsevier　Ltd.　All　rights　reserved.