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author:

Tan, Zunkun (Tan, Zunkun.) [1] | Zhang, Peng (Zhang, Peng.) [2] | Chen, Qiaoshan (Chen, Qiaoshan.) [3] (Scholars:陈巧珊) | Fang, Shengqiong (Fang, Shengqiong.) [4] (Scholars:方圣琼) | Huang, Guocheng (Huang, Guocheng.) [5] (Scholars:黄国城) | Bi, Jinhong (Bi, Jinhong.) [6] (Scholars:毕进红) | Wu, Ling (Wu, Ling.) [7] (Scholars:吴棱)

Indexed by:

EI SCIE

Abstract:

Photocatalytic H-2 production via water splitting has emerged as an eco-friendly and green technology to efficiently utilize solar energy. Developing visible light active photocatalysts, especially the metal-free ones, is crucial to access this technology considering their economic and environmental benefits. Hence, a facile UV reduction method was adopted to fabricate a highly active metal-free photocatalyst by modifying covalent triazine-based frameworks (CTFs) with reduced graphene oxide (rGO). The optimized CTF composite with 2 wt% rGO exhibited a 4.3-fold activity enhancement compared with pristine CTFs, showing a prime H-2 evolution efficiency of 894 mu mol g(-1) h(-1). The contributions of rGO to the photocatalytic system and the interaction between rGO and CTFs were thoroughly studied. The modification of rGO endowed the photocatalyst with improved visible-light absorption, stronger reductive ability, and faster separation rate of photoinduced carriers. Moreover, the covalent C-O-C bond formed in the two components facilitates the directional transfer of photoinduced electrons. A low-cost and robust photocatalyst for clean energy production is constructed in this work, providing inspirations for the design and fabrication of metal-free photocatalytic materials with superior performance.

Keyword:

Community:

  • [ 1 ] [Tan, Zunkun]Fuzhou Univ, Dept Environm Sci & Engn, Minhou 350108, Fujian, Peoples R China
  • [ 2 ] [Zhang, Peng]Fuzhou Univ, Dept Environm Sci & Engn, Minhou 350108, Fujian, Peoples R China
  • [ 3 ] [Chen, Qiaoshan]Fuzhou Univ, Dept Environm Sci & Engn, Minhou 350108, Fujian, Peoples R China
  • [ 4 ] [Fang, Shengqiong]Fuzhou Univ, Dept Environm Sci & Engn, Minhou 350108, Fujian, Peoples R China
  • [ 5 ] [Huang, Guocheng]Fuzhou Univ, Dept Environm Sci & Engn, Minhou 350108, Fujian, Peoples R China
  • [ 6 ] [Bi, Jinhong]Fuzhou Univ, Dept Environm Sci & Engn, Minhou 350108, Fujian, Peoples R China
  • [ 7 ] [Bi, Jinhong]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Minhou 350108, Fujian, Peoples R China
  • [ 8 ] [Wu, Ling]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Minhou 350108, Fujian, Peoples R China

Reprint 's Address:

  • 陈巧珊 毕进红

    [Chen, Qiaoshan]Fuzhou Univ, Dept Environm Sci & Engn, Minhou 350108, Fujian, Peoples R China;;[Bi, Jinhong]Fuzhou Univ, Dept Environm Sci & Engn, Minhou 350108, Fujian, Peoples R China;;[Bi, Jinhong]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Minhou 350108, Fujian, Peoples R China

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Source :

CATALYSIS SCIENCE & TECHNOLOGY

ISSN: 2044-4753

Year: 2021

Issue: 5

Volume: 11

Page: 1874-1880

6 . 1 7 7

JCR@2021

4 . 4 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:117

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 15

SCOPUS Cited Count: 16

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

Online/Total:123/10460012
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