Sodium-ion　batteries　are　a　potential　candidate　for　next-generation　energy　storage　devices.　Unfortunately,　developing　an　anode　with　improved　long-term　cycling　stability　and　high-rate　performance　remains　a　substantial　problem.　In　this　work,　we　develop　that　the　Na+　intercalation　pseudocapacitance　in　faceted　titanium　dioxide　endows　extreme　fast　charging　and　long　cycle　life　in　a　sodium-ion　battery.　Theoretical　calculations　and　comprehensive　characterization　exhibit　that　high　ionic　conductivity,　stable　solid　electrolyte　interphase　(SEI),　and　pseudocapacitive　behavior　are　essential　for　fast　charging.　This　well-designed　electrode　demonstrates　a　significantly　high　reversible　capacity　of　about　135　mAh　g−1　at　90　C　(∼30　A　g−1)　for　10,000　cycles　with　an　87.8%　retension.　Coupled　with　a　vanadium　phosphate　sodium　Na3V2(PO4)3　cathode,　and　this　full　cell　displays　a　specific　capacity　of　310　mAh　g−1　at　0.2　A　g−1　for　100　cycles.　This　study　unveils　the　key　mechanisms　for　fast-charging　sodium　storage,　and　can　also　facilitate　the　improvement　of　other　titanium-based　anodes　secondary　batteries.　©　2023　Elsevier　B.V.