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Recently, Co-based materials have been widely used as a type of supercapacitor. However, Co-based materials are highly restricted due to their low conductivity, poor cyclic performance, and large structural changes during the charge/discharge process. Carbon materials have been found to improve the electrochemistry performance of Co(OH)2. In this work, sulfur doping was used to enhance the electrochemistry performance of Co(OH)2@nitrogen-doped carbon dots (Co(OH)2@NC) via hydrothermal approach. Here, as-prepared S-Co(OH)2@NC shows an excellent specific capacitance of 730 F g−1 at 1 A g−1 (much higher than that of pristine Co(OH)2@NC (592 F g−1 at 1 A g−1)). An asymmetric supercapacitor (ASC) is assembled by S-Co(OH)2@NC (as a positive electrode) and graphene aerogels@NC (as a negative electrode), which presents a specific energy density as high as 39.59 Wh kg−1 with a power density of 639 W kg−1. Moreover, the ACS manifests extraordinary cycle stability (75% capacitance retention after 8500 cycles). In summary, sulfur doping in electrode material has been proven as an efficient approach for improving the electrochemical performance in supercapacitor devices. © 2023, The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.
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Ionics
ISSN: 0947-7047
Year: 2023
Issue: 8
Volume: 29
Page: 3249-3259
2 . 4
JCR@2023
2 . 4 0 0
JCR@2023
ESI HC Threshold:30
JCR Journal Grade:3
CAS Journal Grade:4
Cited Count:
SCOPUS Cited Count: 1
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
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