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author:

Wu, X. (Wu, X..) [1] | Yu, F. (Yu, F..) [2] | Xiong, R. (Xiong, R..) [3] | Wang, P. (Wang, P..) [4] | Zhou, P. (Zhou, P..) [5] | Sa, B. (Sa, B..) [6] | Lin, C. (Lin, C..) [7] | Zhao, C. (Zhao, C..) [8] | Gao, M. (Gao, M..) [9] | Zhang, Q. (Zhang, Q..) [10]

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Scopus

Abstract:

A combination of transparency and photochromic (PC) properties in ferroelectrics has promising application potential in smart windows and optical storage/imaging. Nonetheless, limited by understanding the underlying PC mechanism, a splendid PC performance is rarely achieved in transparent ferroelectrics. Here, a strategy to construct deep-lying traps by ion-doping induced defect engineering in (K0.5Na0.5)NbO3-based ferroelectric ceramics is proposed. Based on the improved density functional theory simulations, a high concentration of vacancy defects can be realized by codoping 1 mol % Pr and 4 mol % Ba in (K0.5Na0.5)NbO3, which helps achieving deep-lying traps and then superior PC performance. Through traditional pressureless sintering, highly transparent ceramics with designed optimal composition have been fabricated in a wide sintering temperature range (1170-1210 °C), exhibiting an ultrafast PC feature, i.e., 0.1 s response time (by illumination of 400 nm light), along with high PC efficiency (5.8 cm2·W-1) and PC rate (7.1 s-1), preeminent among reported inorganic PC transparent materials. Additionally, the ceramics have been utilized for real-time optical recording, displaying unambiguous patterning with long-time preservation (21 days). This research supplies a paradigm for designing high-performance PC transparent materials in optical applications and helps deepen the comprehensive understanding of the PC mechanism. © 2023 American Chemical Society.

Keyword:

deep-lying traps (K0.5Na0.5)NbO3 real-time optical recording transparent ceramics ultrahigh photochromic rate

Community:

  • [ 1 ] [Wu X.]College of Materials Science and Engineering, Fuzhou University, Fuzhou, 350108, China
  • [ 2 ] [Yu F.]College of Materials Science and Engineering, Fuzhou University, Fuzhou, 350108, China
  • [ 3 ] [Xiong R.]College of Materials Science and Engineering, Fuzhou University, Fuzhou, 350108, China
  • [ 4 ] [Wang P.]College of Materials Science and Engineering, Fuzhou University, Fuzhou, 350108, China
  • [ 5 ] [Zhou P.]College of Materials Science and Engineering, Fuzhou University, Fuzhou, 350108, China
  • [ 6 ] [Sa B.]College of Materials Science and Engineering, Fuzhou University, Fuzhou, 350108, China
  • [ 7 ] [Lin C.]College of Materials Science and Engineering, Fuzhou University, Fuzhou, 350108, China
  • [ 8 ] [Zhao C.]College of Materials Science and Engineering, Fuzhou University, Fuzhou, 350108, China
  • [ 9 ] [Gao M.]College of Materials Science and Engineering, Fuzhou University, Fuzhou, 350108, China
  • [ 10 ] [Zhang Q.]School of Materials and Metallurgy, Inner Mongolia University of Science and Technology, Baotou, 014010, China

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Source :

ACS Applied Materials and Interfaces

ISSN: 1944-8244

Year: 2023

Issue: 13

Volume: 15

Page: 16828-16841

8 . 5

JCR@2023

8 . 5 0 0

JCR@2023

ESI HC Threshold:49

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 21

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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