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A combination of transparency and photochromic (PC) properties in ferroelectrics has promising application potential in smart windows and optical storage/imaging. Nonetheless, limited by understanding the underlying PC mechanism, a splendid PC performance is rarely achieved in transparent ferroelectrics. Here, a strategy to construct deep-lying traps by ion-doping induced defect engineering in (K0.5Na0.5)- NbO3-based ferroelectric ceramics is proposed. Based on the improved density functional theory simulations, a high concentration of vacancy defects can be realized by codoping 1 mol % Pr and 4 mol % Ba in (K0.5Na0.5)NbO3, which helps achieving deep-lying traps and then superior PC performance. Through traditional pressureless sintering, highly transparent ceramics with designed optimal composition have been fabricated in a wide sintering temperature range (1170-1210 degrees C), exhibiting an ultrafast PC feature, i.e., 0.1 s response time (by illumination of 400 nm light), along with high PC efficiency (5.8 cm2 center dot W-1) and PC rate (7.1 s-1), preeminent among reported inorganic PC transparent materials. Additionally, the ceramics have been utilized for real-time optical recording, displaying unambiguous patterning with long-time preservation (21 days). This research supplies a paradigm for designing high-performance PC transparent materials in optical applications and helps deepen the comprehensive understanding of the PC mechanism.
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ACS APPLIED MATERIALS & INTERFACES
ISSN: 1944-8244
Year: 2023
Issue: 13
Volume: 15
Page: 16828-16841
8 . 5
JCR@2023
8 . 5 0 0
JCR@2023
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:49
JCR Journal Grade:1
CAS Journal Grade:2
Cited Count:
WoS CC Cited Count: 27
SCOPUS Cited Count: 26
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
Affiliated Colleges: