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author:

Wu, Xiao (Wu, Xiao.) [1] (Scholars:吴啸) | Yu, Fangyuan (Yu, Fangyuan.) [2] | Xiong, Rui (Xiong, Rui.) [3] | Wang, Peng (Wang, Peng.) [4] | Zhou, Ping (Zhou, Ping.) [5] | Sa, Baisheng (Sa, Baisheng.) [6] (Scholars:萨百晟) | Lin, Cong (Lin, Cong.) [7] (Scholars:林枞) | Zhao, Chunlin (Zhao, Chunlin.) [8] (Scholars:赵纯林) | Gao, Min (Gao, Min.) [9] (Scholars:高旻) | Zhang, Qiwei (Zhang, Qiwei.) [10]

Indexed by:

EI Scopus SCIE

Abstract:

A combination of transparency and photochromic (PC) properties in ferroelectrics has promising application potential in smart windows and optical storage/imaging. Nonetheless, limited by understanding the underlying PC mechanism, a splendid PC performance is rarely achieved in transparent ferroelectrics. Here, a strategy to construct deep-lying traps by ion-doping induced defect engineering in (K0.5Na0.5)- NbO3-based ferroelectric ceramics is proposed. Based on the improved density functional theory simulations, a high concentration of vacancy defects can be realized by codoping 1 mol % Pr and 4 mol % Ba in (K0.5Na0.5)NbO3, which helps achieving deep-lying traps and then superior PC performance. Through traditional pressureless sintering, highly transparent ceramics with designed optimal composition have been fabricated in a wide sintering temperature range (1170-1210 degrees C), exhibiting an ultrafast PC feature, i.e., 0.1 s response time (by illumination of 400 nm light), along with high PC efficiency (5.8 cm2 center dot W-1) and PC rate (7.1 s-1), preeminent among reported inorganic PC transparent materials. Additionally, the ceramics have been utilized for real-time optical recording, displaying unambiguous patterning with long-time preservation (21 days). This research supplies a paradigm for designing high-performance PC transparent materials in optical applications and helps deepen the comprehensive understanding of the PC mechanism.

Keyword:

5Na0 5)NbO3 deep-lying traps (K0 real-time optical recording transparent ceramics ultrahigh photochromic rate

Community:

  • [ 1 ] [Wu, Xiao]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 2 ] [Yu, Fangyuan]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 3 ] [Xiong, Rui]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 4 ] [Wang, Peng]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 5 ] [Zhou, Ping]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 6 ] [Sa, Baisheng]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 7 ] [Lin, Cong]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 8 ] [Zhao, Chunlin]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 9 ] [Gao, Min]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 10 ] [Zhang, Qiwei]Inner Mongolia Univ Sci & Technol, Sch Mat & Met, Baotou 014010, Peoples R China

Reprint 's Address:

  • [Wu, Xiao]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China;;[Sa, Baisheng]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China;;

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Source :

ACS APPLIED MATERIALS & INTERFACES

ISSN: 1944-8244

Year: 2023

Issue: 13

Volume: 15

Page: 16828-16841

8 . 5

JCR@2023

8 . 5 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:49

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 27

SCOPUS Cited Count: 26

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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