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author:

Liang, Y. (Liang, Y..) [1] | Wang, J. (Wang, J..) [2] | Tian, Z. (Tian, Z..) [3] | Shang, K. (Shang, K..) [4] | Hu, X. (Hu, X..) [5] | Yu, J. (Yu, J..) [6] | Cai, P. (Cai, P..) [7] | Liu, Y. (Liu, Y..) [8] | Yuan, J. (Yuan, J..) [9] | Ding, Y. (Ding, Y..) [10] | Wen, Z. (Wen, Z..) [11]

Indexed by:

Scopus

Abstract:

Zn ion energy storage devices have received widespread attention because of their high safety, environmental friendliness, low cost, and high energy density. However, Zn metal anodes usually suffer from disadvantages such as dendrite growth, low coulombic efficiency, and volume expansion during plating/stripping, which severely hampers the practical applications. Here, we construct 3D Zn frameworks by exploring different conductive hosts and modify 3D hosts by plating Sn to suppress Zn dendrites and side reactions. The electrode which optimized by electroplating Zn after chemically plating Sn on Cu foam (Sn−Cu foam@Zn) exhibits stable polarization voltage distribution and almost 100% coulombic efficiency over 200 cycles of Zn plating/stripping. Furthermore, when pairing with V2O5 cathode, the full cell showed fast reaction kinetics and a capacity of 113 mAh g−1 after 1000 cycles at a current density of 1 A g−1, which is 90.4% of the initial capacity. This work provides a new strategy for the development of high-performance Zn anodes. © 2023 Wiley-VCH GmbH.

Keyword:

3D electrodeposited host aqueous zinc-ion battery dendrite surface modification Zn anode

Community:

  • [ 1 ] [Liang, Y.]College of Chemical Engineering, Fuzhou University, Fuzhou, 350108, China
  • [ 2 ] [Liang, Y.]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Provincial Key Laboratory of Materials and Techniques toward Hydrogen Energy, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
  • [ 3 ] [Wang, J.]College of Chemical Engineering, Fuzhou University, Fuzhou, 350108, China
  • [ 4 ] [Wang, J.]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Provincial Key Laboratory of Materials and Techniques toward Hydrogen Energy, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
  • [ 5 ] [Tian, Z.]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Provincial Key Laboratory of Materials and Techniques toward Hydrogen Energy, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
  • [ 6 ] [Tian, Z.]College of Materials Science and Engineering, Fujian Normal University, Fujian, Fuzhou, 350007, China
  • [ 7 ] [Shang, K.]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Provincial Key Laboratory of Materials and Techniques toward Hydrogen Energy, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
  • [ 8 ] [Hu, X.]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Provincial Key Laboratory of Materials and Techniques toward Hydrogen Energy, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
  • [ 9 ] [Yu, J.]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Provincial Key Laboratory of Materials and Techniques toward Hydrogen Energy, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
  • [ 10 ] [Cai, P.]Fujian Provincial Key Laboratory of Advanced Inorganic Oxygenated-Materials, College of Chemistry, Fuzhou University, Fujian, Fuzhou, 350108, China
  • [ 11 ] [Liu, Y.]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Provincial Key Laboratory of Materials and Techniques toward Hydrogen Energy, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
  • [ 12 ] [Yuan, J.]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Provincial Key Laboratory of Materials and Techniques toward Hydrogen Energy, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
  • [ 13 ] [Ding, Y.]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Provincial Key Laboratory of Materials and Techniques toward Hydrogen Energy, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
  • [ 14 ] [Wen, Z.]College of Chemical Engineering, Fuzhou University, Fuzhou, 350108, China
  • [ 15 ] [Wen, Z.]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Provincial Key Laboratory of Materials and Techniques toward Hydrogen Energy, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China

Reprint 's Address:

  • [Wen, Z.]College of Chemical Engineering, China

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Source :

ChemNanoMat

ISSN: 2199-692X

Year: 2023

Issue: 4

Volume: 9

2 . 6

JCR@2023

2 . 6 0 0

JCR@2023

ESI HC Threshold:49

JCR Journal Grade:2

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 1

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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