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author:

Wu, Lina (Wu, Lina.) [1] | Wang, Huiping (Wang, Huiping.) [2] | Kong, Xiangqian (Kong, Xiangqian.) [3] | Wei, Haibo (Wei, Haibo.) [4] | Chen, Sheng (Chen, Sheng.) [5] | Chi, Lisheng (Chi, Lisheng.) [6]

Indexed by:

EI Scopus SCIE

Abstract:

Effective removal of strontium isotopes in radioactive waste streams has important implications for the environment and the sustainable development of nuclear energy. In this work, a zirconium phosphate/18-crown-ether-6 (ZrP/18C6) composite was prepared using the intercalation method by loading crown ether into zirconium phosphate. The composite was structurally and morphologically characterized by XRD, FT-IR, XPS, and SEM. The adsorption experiments of Sr2+ onto the ZrP/18C6 composite were conducted as a function of temperature, pH, Sr2+ concentration and competing ions. The results indicate ZrP/18C6 can adsorb 98.6% of Sr2+ within 30 minutes at an Sr2+ concentration of 100 mg L-1 and maintain a high removal rate with a distribution coefficient of 7 x 10(5) mL g(-1) when Sr2+ is at a low level of 4.28 mg L-1. The ZrP/18C6 composite reached a maximum adsorption capacity of 195.74 mg g(-1) at an Sr2+ concentration of 380 mg L-1, which is significantly higher than the 43.03 mg g(-1) of alpha-ZrP. The adsorption performance of Sr2+ onto ZrP/18C6 is not significantly affected by temperature, pH and competing ions. Furthermore, the adsorption kinetics and thermodynamics were analyzed based on the adsorption data obtained in the present work. It is shown that the adsorption of Sr2+ onto ZrP/18C6 follows the pseudo-second-order model and the Langmuir monolayer model, respectively. Additionally, the adsorption mechanism of Sr2+ by ZrP/18C6 is discussed.

Keyword:

Community:

  • [ 1 ] [Wu, Lina]Fuzhou Univ, Coll Chem, Fuzhou 350108, Fujian, Peoples R China
  • [ 2 ] [Wu, Lina]Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350116, Peoples R China
  • [ 3 ] [Wang, Huiping]Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350116, Peoples R China
  • [ 4 ] [Kong, Xiangqian]Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350116, Peoples R China
  • [ 5 ] [Wei, Haibo]Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350116, Peoples R China
  • [ 6 ] [Chen, Sheng]Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350116, Peoples R China
  • [ 7 ] [Chi, Lisheng]Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350116, Peoples R China
  • [ 8 ] [Wu, Lina]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Fuel & Mat Clean Nucl Energy Syst, Fuzhou 350002, Fujian, Peoples R China
  • [ 9 ] [Wang, Huiping]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Fuel & Mat Clean Nucl Energy Syst, Fuzhou 350002, Fujian, Peoples R China
  • [ 10 ] [Kong, Xiangqian]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Fuel & Mat Clean Nucl Energy Syst, Fuzhou 350002, Fujian, Peoples R China
  • [ 11 ] [Wei, Haibo]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Fuel & Mat Clean Nucl Energy Syst, Fuzhou 350002, Fujian, Peoples R China
  • [ 12 ] [Chen, Sheng]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Fuel & Mat Clean Nucl Energy Syst, Fuzhou 350002, Fujian, Peoples R China
  • [ 13 ] [Chi, Lisheng]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Fuel & Mat Clean Nucl Energy Syst, Fuzhou 350002, Fujian, Peoples R China

Reprint 's Address:

  • [Wang, Huiping]Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350116, Peoples R China;;[Chi, Lisheng]Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350116, Peoples R China;;[Wang, Huiping]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Fuel & Mat Clean Nucl Energy Syst, Fuzhou 350002, Fujian, Peoples R China;;[Chi, Lisheng]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Fuel & Mat Clean Nucl Energy Syst, Fuzhou 350002, Fujian, Peoples R China;;

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RSC ADVANCES

ISSN: 2046-2069

Year: 2023

Issue: 10

Volume: 13

Page: 6346-6355

3 . 9

JCR@2023

3 . 9 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:39

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 5

SCOPUS Cited Count: 5

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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