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author:

Li, S. (Li, S..) [1] | Mo, Q.-L. (Mo, Q.-L..) [2] | Xiao, Y. (Xiao, Y..) [3] | Xiao, F.-X. (Xiao, F.-X..) [4]

Indexed by:

Scopus

Abstract:

Cuprous oxide (Cu2O)-based photocathodes have been attracting enduring interest for green and sustainable solar fuel production by solar-driven photoelectrochemical (PEC) water splitting and CO2 reduction reactions. Although Cu2O is featured by the theoretically outstanding photoactivity owing to the favorable band-gap and appropriate band alignment, wide-spread utilization of Cu2O is largely hampered by its severe photo-corrosion and difficulty in charge transfer/separation modulation, hence rendering fabricating robust, stable and high-efficiency Cu2O-based photoelectrodes a continuously challenging issue. In this review, fundamentals of PEC reactions including water splitting and CO2 reduction are concisely elucidated, and then diverse strategies for constructing a large variety of quintessential Cu2O-based photocathodes are comprehensively summarized. Subsequently, predominant Cu2O-based photocathodes currently being extensively explored in PEC water splitting and CO2 reduction reactions are specifically introduced. Finally, future perspective and outlook of Cu2O-based photocathodes in these two booming research fields are forecasted. Our review could provide enriched information on rational design and utilization of Cu2O-based photocathodes for solar fuel production. © 2022 Elsevier B.V.

Keyword:

Cu2O PEC Photocatalytic CO2 reduction Photocatalytic Water Splitting Photocathode

Community:

  • [ 1 ] [Li, S.]College of Materials Science and Engineering, Fuzhou University, New Campus, Fujian Province, Minhou, 350108, China
  • [ 2 ] [Mo, Q.-L.]College of Materials Science and Engineering, Fuzhou University, New Campus, Fujian Province, Minhou, 350108, China
  • [ 3 ] [Xiao, Y.]College of Materials Science and Engineering, Fuzhou University, New Campus, Fujian Province, Minhou, 350108, China
  • [ 4 ] [Xiao, F.-X.]College of Materials Science and Engineering, Fuzhou University, New Campus, Fujian Province, Minhou, 350108, China
  • [ 5 ] [Xiao, F.-X.]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fujian, Fuzhou, 350108, China

Reprint 's Address:

  • [Xiao, F.-X.]College of Materials Science and Engineering, New Campus, Fujian Province, China

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Source :

Coordination Chemistry Reviews

ISSN: 0010-8545

Year: 2023

Volume: 477

2 0 . 3

JCR@2023

2 0 . 3 0 0

JCR@2023

ESI HC Threshold:39

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 18

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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