Indexed by:
Abstract:
Cuprous oxide (Cu2O)-based photocathodes have been attracting enduring interest for green and sustainable solar fuel production by solar-driven photoelectrochemical (PEC) water splitting and CO2 reduction reactions. Although Cu2O is featured by the theoretically outstanding photoactivity owing to the favorable band-gap and appropriate band alignment, wide-spread utilization of Cu2O is largely hampered by its severe photo-corrosion and difficulty in charge transfer/separation modulation, hence rendering fabricating robust, stable and high-efficiency Cu2O-based photoelectrodes a continuously challenging issue. In this review, fundamentals of PEC reactions including water splitting and CO2 reduction are concisely elucidated, and then diverse strategies for constructing a large variety of quintessential Cu2O-based photocathodes are comprehensively summarized. Subsequently, predominant Cu2O-based photocathodes currently being extensively explored in PEC water splitting and CO2 reduction reactions are specifically introduced. Finally, future perspective and outlook of Cu2O-based photocathodes in these two booming research fields are forecasted. Our review could provide enriched information on rational design and utilization of Cu2O-based photocathodes for solar fuel production. © 2022 Elsevier B.V.
Keyword:
Reprint 's Address:
Email:
Source :
Coordination Chemistry Reviews
ISSN: 0010-8545
Year: 2023
Volume: 477
2 0 . 3
JCR@2023
2 0 . 3 0 0
JCR@2023
ESI HC Threshold:39
JCR Journal Grade:1
CAS Journal Grade:1
Cited Count:
SCOPUS Cited Count: 18
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 2
Affiliated Colleges: