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author:

Zheng, L. (Zheng, L..) [1] | Wang, Y. (Wang, Y..) [2] | Zhu, Z. (Zhu, Z..) [3] | You, Z. (You, Z..) [4] | Li, J. (Li, J..) [5] | Sun, Y. (Sun, Y..) [6] | Lakshminarayana, G. (Lakshminarayana, G..) [7] | Tu, C. (Tu, C..) [8]

Indexed by:

Scopus

Abstract:

2 at.% Dy3+: BaF2 and 2 at.% Dy3+/2 at.% RE3+(RE3+ = Gd3+, Y3+, Lu3+): BaF2 single crystals were grown by the Bridgman-Stockbarger method, and characterized by absorption, visible emission, and fluorescence decay curves. Also, relying on the excitation and emission spectra, decay curves at low temperature (77 K) for Dy3+: BaF2 and Dy3+/RE3+(RE3+ = Gd3+, Y3+, Lu3+): BaF2 crystals have been measured. We found that Dy ions have at least three lattice sites in BaF2 crystal, and the lattice sites of Dy3+ ions can be reduced by co-doping with Gd3+, Y3+ or Lu3+ ions, where Dy3+: BaF2 and Dy3+/RE3+(RE3+ = Gd3+, Y3+, Lu3+): BaF2 single crystals can be considered as quasi-single lattice crystals. From visible fluorescence spectra, it was found that co-doping Gd3+ will increase the emission intensity of yellow light by 20 times, co-doping Y3+ will increase the emission intensity of yellow light by 30 times, and co-doping Lu3+ will increase the emission intensity of yellow light by 25 times. The calculated absorption cross-section, emission cross-section, and fluorescence lifetimes indicate that Dy3+: BaF2 and Dy3+/RE3+(RE3+ = Gd3+, Y3+, Lu3+): BaF2 crystals especially, Dy3+/Y3+: BaF2 crystals are suitable to achieve yellow laser output. © 2022

Keyword:

BaF2 crystal Co-doping Dy3+ Fluorescence Lattice sites Yellow laser

Community:

  • [ 1 ] [Zheng, L.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 2 ] [Zheng, L.]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian Province, Fuzhou City, 350002, China
  • [ 3 ] [Zheng, L.]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China (Mindu Innovation Laboratory), Fujian, Fuzhou, 350108, China
  • [ 4 ] [Wang, Y.]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian Province, Fuzhou City, 350002, China
  • [ 5 ] [Wang, Y.]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China (Mindu Innovation Laboratory), Fujian, Fuzhou, 350108, China
  • [ 6 ] [Zhu, Z.]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian Province, Fuzhou City, 350002, China
  • [ 7 ] [Zhu, Z.]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China (Mindu Innovation Laboratory), Fujian, Fuzhou, 350108, China
  • [ 8 ] [You, Z.]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian Province, Fuzhou City, 350002, China
  • [ 9 ] [You, Z.]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China (Mindu Innovation Laboratory), Fujian, Fuzhou, 350108, China
  • [ 10 ] [Li, J.]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian Province, Fuzhou City, 350002, China
  • [ 11 ] [Li, J.]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China (Mindu Innovation Laboratory), Fujian, Fuzhou, 350108, China
  • [ 12 ] [Sun, Y.]Faculty of Materials Metallurgy and Chemical, Jiangxi University of Science and Technology, Jiangxi, Ganzhou, 341000, China
  • [ 13 ] [Lakshminarayana, G.]Intelligent Construction Automation Center, Kyungpook National University, 80, Daehak-ro, Buk-gu, Daegu, 41566, South Korea
  • [ 14 ] [Tu, C.]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian Province, Fuzhou City, 350002, China
  • [ 15 ] [Tu, C.]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China (Mindu Innovation Laboratory), Fujian, Fuzhou, 350108, China

Reprint 's Address:

  • [Tu, C.]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Province, China

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Source :

Journal of Luminescence

ISSN: 0022-2313

Year: 2023

Volume: 255

3 . 3

JCR@2023

3 . 3 0 0

JCR@2023

ESI HC Threshold:30

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 2

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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