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1 at% Dy3+: CaF2 and 1 at% Dy3+/5 at% Y3+: CaF2 crystals were grown by Bridgman method. Absorptions, visible and mid-infrared emissions, and fluorescence decay curves were measured. By applying Judd-Ofelt (J-O) theory, for Dy3+/Y3+: CaF2 crystal stronger oscillator strength and radiation transition probability were derived. The effect of Y(3+)ions incorporation into CaF2 crystals on the light emission of Dy3+ ions was discussed. Co-doped Y3+ ions can destroy Dy clusters, cripple the concentration quenching effect, and enhance the yellow and mid-infrared fluorescence intensity. The yellow fluorescence intensity of Dy3+/Y3+: CaF2 is similar to 70 times higher than that of Dy3+: CaF2 crystal. The local structure of Dy3+ ions was analyzed, and co-doping Y3+ can increase the quantity of tetragonal Dy clusters. In Dy3+/Y3+: CaF2 crystal, the tetragonal Dy clusters occupy the dominant position, and the fluorescence lifetime (tau(f)) is relatively short. It can be concluded that Dy3+: CaF2 and Dy3+/Y3+: CaF2 crystals are expected to achieve yellow and mid-infrared laser output simultaneously. (C) 2020 Elsevier B.V. All rights reserved.
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JOURNAL OF ALLOYS AND COMPOUNDS
ISSN: 0925-8388
Year: 2021
Volume: 856
6 . 3 7 1
JCR@2021
5 . 8 0 0
JCR@2023
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:142
JCR Journal Grade:1
CAS Journal Grade:2
Cited Count:
WoS CC Cited Count: 0
SCOPUS Cited Count: 21
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
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