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author:

Gao, Xiangqi (Gao, Xiangqi.) [1] | Fang, Gaoyang (Fang, Gaoyang.) [2] | Wang, Yan (Wang, Yan.) [3] | Zhu, Zhaojie (Zhu, Zhaojie.) [4] | You, Zhenyu (You, Zhenyu.) [5] | Li, Jianfu (Li, Jianfu.) [6] | Sun, Yijian (Sun, Yijian.) [7] | Tu, Chaoyang (Tu, Chaoyang.) [8]

Indexed by:

EI SCIE

Abstract:

1 at% Dy3+: CaF2 and 1 at% Dy3+/5 at% Y3+: CaF2 crystals were grown by Bridgman method. Absorptions, visible and mid-infrared emissions, and fluorescence decay curves were measured. By applying Judd-Ofelt (J-O) theory, for Dy3+/Y3+: CaF2 crystal stronger oscillator strength and radiation transition probability were derived. The effect of Y(3+)ions incorporation into CaF2 crystals on the light emission of Dy3+ ions was discussed. Co-doped Y3+ ions can destroy Dy clusters, cripple the concentration quenching effect, and enhance the yellow and mid-infrared fluorescence intensity. The yellow fluorescence intensity of Dy3+/Y3+: CaF2 is similar to 70 times higher than that of Dy3+: CaF2 crystal. The local structure of Dy3+ ions was analyzed, and co-doping Y3+ can increase the quantity of tetragonal Dy clusters. In Dy3+/Y3+: CaF2 crystal, the tetragonal Dy clusters occupy the dominant position, and the fluorescence lifetime (tau(f)) is relatively short. It can be concluded that Dy3+: CaF2 and Dy3+/Y3+: CaF2 crystals are expected to achieve yellow and mid-infrared laser output simultaneously. (C) 2020 Elsevier B.V. All rights reserved.

Keyword:

CaF2 crystal Dy3+ J-O theory Spectroscopic features Y3+

Community:

  • [ 1 ] [Gao, Xiangqi]Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Optoelect Mat Chem & Phys, Fuzhou 350002, Fujian, Peoples R China
  • [ 2 ] [Fang, Gaoyang]Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Optoelect Mat Chem & Phys, Fuzhou 350002, Fujian, Peoples R China
  • [ 3 ] [Wang, Yan]Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Optoelect Mat Chem & Phys, Fuzhou 350002, Fujian, Peoples R China
  • [ 4 ] [Zhu, Zhaojie]Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Optoelect Mat Chem & Phys, Fuzhou 350002, Fujian, Peoples R China
  • [ 5 ] [You, Zhenyu]Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Optoelect Mat Chem & Phys, Fuzhou 350002, Fujian, Peoples R China
  • [ 6 ] [Li, Jianfu]Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Optoelect Mat Chem & Phys, Fuzhou 350002, Fujian, Peoples R China
  • [ 7 ] [Tu, Chaoyang]Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Optoelect Mat Chem & Phys, Fuzhou 350002, Fujian, Peoples R China
  • [ 8 ] [Gao, Xiangqi]Fujian Normal Univ, Coll Chem & Mat Sci, Fuzhou 350007, Fujian, Peoples R China
  • [ 9 ] [Gao, Xiangqi]Mindu Innovat Lab, Fujian Sci & Technol Innovat Lab Optoelect Inform, Fuzhou 350108, Fujian, Peoples R China
  • [ 10 ] [Fang, Gaoyang]Mindu Innovat Lab, Fujian Sci & Technol Innovat Lab Optoelect Inform, Fuzhou 350108, Fujian, Peoples R China
  • [ 11 ] [Wang, Yan]Mindu Innovat Lab, Fujian Sci & Technol Innovat Lab Optoelect Inform, Fuzhou 350108, Fujian, Peoples R China
  • [ 12 ] [Zhu, Zhaojie]Mindu Innovat Lab, Fujian Sci & Technol Innovat Lab Optoelect Inform, Fuzhou 350108, Fujian, Peoples R China
  • [ 13 ] [You, Zhenyu]Mindu Innovat Lab, Fujian Sci & Technol Innovat Lab Optoelect Inform, Fuzhou 350108, Fujian, Peoples R China
  • [ 14 ] [Li, Jianfu]Mindu Innovat Lab, Fujian Sci & Technol Innovat Lab Optoelect Inform, Fuzhou 350108, Fujian, Peoples R China
  • [ 15 ] [Tu, Chaoyang]Mindu Innovat Lab, Fujian Sci & Technol Innovat Lab Optoelect Inform, Fuzhou 350108, Fujian, Peoples R China
  • [ 16 ] [Fang, Gaoyang]Fuzhou Univ, Coll Chem, Fuzhou 350116, Fujian, Peoples R China
  • [ 17 ] [Sun, Yijian]Jiangxi Univ Sci & Technol, Fac Mat Met & Chem, Ganzhou 341000, Jiangxi, Peoples R China

Reprint 's Address:

  • [Tu, Chaoyang]Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Optoelect Mat Chem & Phys, Fuzhou 350002, Fujian, Peoples R China

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Source :

JOURNAL OF ALLOYS AND COMPOUNDS

ISSN: 0925-8388

Year: 2021

Volume: 856

6 . 3 7 1

JCR@2021

5 . 8 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:142

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 21

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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