The　kinetics　incompatibility　between　battery-type　anode　and　capacitive-type　cathode　for　sodium　ion　hybrid　capacitors　(SIHCs)　seriously　hinders　their　overall　performance　output.　Herein,　we　construct　a　SIHCs　device　by　coupling　with　quantum　grade　vanadium　nitride　(VN)　nanodots　anchored　in　one-dimensional　N/F　co-doped　carbon　nanofiber　cages　hybrids　(VNQDs@PCNFs-N/F)　as　the　freestanding　anode　and　the　corresponding　activated　N/F　co-doped　carbon　nanofiber　cages　(APCNFs-N/F)　as　cathode.　The　strong　coupling　of　VN　quantum　dots　with　N/F　co-doped　1D　conductive　carbon　cages　effectively　facilitates　the　ion/electron　transport　and　intercalation-conversion-deintercalation　reactions,　ensuring　fast　sodium　storage　to　surmount　aforesaid　kinetics　incompatibility.　Additionally,　density　functional　theory　calculations　cogently　manifest　that　the　abundant　active　sites　in　the　VNQDs@PCNFs-N/F　configuration　boost　the　Na+　adsorption/reaction　activity　well　which　will　promote　both　＇intrinsic＇and　＇extrinsic＇pseudocapacitance　and　further　improve　anode　kinetics.　Consequently,　the　assembled　SIHCs　device　can　achieve　high　energy　densities　of　157.1　and　95.0　Wh　kg-1　at　power　densities　of　198.8　and　9100.5　W　kg-1,　respectively,　with　an　ultralong　cycling　life　over　8000　cycles.　This　work　further　verified　the　feasibility　of　kinetics-compatible　electrode　design　strategy　toward　metal　ion　hybrid　capacitors.　©　2022　American　Chemical　Society.