• Complex
  • Title
  • Keyword
  • Abstract
  • Scholars
  • Journal
  • ISSN
  • Conference
成果搜索

author:

Dong, Shaofeng (Dong, Shaofeng.) [1] | Tan, Zunkun (Tan, Zunkun.) [2] | Chen, Qiaoshan (Chen, Qiaoshan.) [3] | Huang, Guocheng (Huang, Guocheng.) [4] | Wu, Ling (Wu, Ling.) [5] | Bi, Jinhong (Bi, Jinhong.) [6]

Indexed by:

EI

Abstract:

Photocatalysis offers a sustainable paradigm for solar-to-fuel conversion because it conflates the merits of renewable solar energy and reusable catalysts. However, the seek for robust photocatalysts that can utilize the full visible light spectrum remains challenging. Herein, cobalt quantum dots (Co QDs) were integrated into ultra-narrow bandgap dioxin linked covalent organic frameworks (COF-318) for photocatalytic solar-to-fuel conversion under full spectrum of visible light irradiation. The optimal Co10-COF exhibited superior photocatalytic CO2 reduction performance, affording a CO yield of 4232 µmolg−1h−1 and H2 evolution of 6611 µmolg−1h−1. Specifically, Co QDs played a crucial role in boosting the photocatalytic performance, which acted as electron collectors to capture the photoinduced electrons and then conveyed them to CO2 molecules. Moreover, the Co QDs modification significantly improved the CO2 adsorption and activation capacity, as well as prolonging the lifetime of photogenerated carriers. This work reveals an operable pathway for fabricating promising photocatalyst for visible-light-driven solar-to-fuel generation and provides insight into the impact of the integration of Co QDs on COF-based photocatalysts. © 2022 Elsevier Inc.

Keyword:

Carbon dioxide Electrons Energy gap Fuels Light Nanocrystals Organic pollutants Photocatalytic activity Semiconductor quantum dots Solar energy

Community:

  • [ 1 ] [Dong, Shaofeng]Department of Environmental Science and Engineering, Fuzhou University, Fujian, Minhou; 350108, China
  • [ 2 ] [Tan, Zunkun]Department of Environmental Science and Engineering, Fuzhou University, Fujian, Minhou; 350108, China
  • [ 3 ] [Chen, Qiaoshan]Department of Environmental Science and Engineering, Fuzhou University, Fujian, Minhou; 350108, China
  • [ 4 ] [Huang, Guocheng]Department of Environmental Science and Engineering, Fuzhou University, Fujian, Minhou; 350108, China
  • [ 5 ] [Wu, Ling]State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fujian, Minhou; 350108, China
  • [ 6 ] [Bi, Jinhong]Department of Environmental Science and Engineering, Fuzhou University, Fujian, Minhou; 350108, China
  • [ 7 ] [Bi, Jinhong]State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fujian, Minhou; 350108, China

Reprint 's Address:

Email:

Show more details

Related Keywords:

Source :

Journal of Colloid and Interface Science

ISSN: 0021-9797

Year: 2022

Volume: 628

Page: 573-582

9 . 9

JCR@2022

9 . 4 0 0

JCR@2023

ESI HC Threshold:74

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 15

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

Affiliated Colleges:

Online/Total:139/10269934
Address:FZU Library(No.2 Xuyuan Road, Fuzhou, Fujian, PRC Post Code:350116) Contact Us:0591-22865326
Copyright:FZU Library Technical Support:Beijing Aegean Software Co., Ltd. 闽ICP备05005463号-1