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author:

Cai, Pingwei (Cai, Pingwei.) [1] | Chen, Kai (Chen, Kai.) [2] | Lu, Zhiwen (Lu, Zhiwen.) [3] | Mondal, Ritwik (Mondal, Ritwik.) [4] | Thotiyl, Musthafa Ottakam (Thotiyl, Musthafa Ottakam.) [5] | Wen, Zhenhai (Wen, Zhenhai.) [6]

Indexed by:

EI Scopus SCIE

Abstract:

Aqueous Zn-based batteries hold multiple advantages of eco-friendliness, easy accessibility, high safety, easy fabrication, and fast kinetics, while their widespread applications have been greatly limited by the relatively narrow thermodynamically stable potential windows (i. e., 1.23 V) of water and the mismatched pH conditions between cathode and anode, which presents challenges regarding how to maximize the output voltage and the energy density. Recently, aqueous OH-/H+ dual-ion Zn-based batteries (OH-/H+-DIZBs), where the Zn anode reacts with hydroxide ions (OH-) in alkaline electrolyte while hydrogen ions (H+) are involved in the cathode reaction in the acidic electrolyte, have been reported to be capable of broadening the working voltage and improving the energy density, which offers practical feasibility toward overcoming the above limitations. This Review thus takes this chance to investigate the recent progress on aqueous OH-/H+-DIZBs. First, the concept and the history of such OH-/H+-DIZBs are introduced, and then special emphasis is put on the working mechanisms, the progress of the development of new batteries, and how the electrolytes improve their performance. Finally, the challenges and opportunities in this field are discussed.

Keyword:

batteries dual-ion battery electrochemistry energy storage high voltage

Community:

  • [ 1 ] [Cai, Pingwei]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Prov Key Lab Nanomat, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Peoples R China
  • [ 2 ] [Chen, Kai]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Prov Key Lab Nanomat, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Peoples R China
  • [ 3 ] [Lu, Zhiwen]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Prov Key Lab Nanomat, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Peoples R China
  • [ 4 ] [Wen, Zhenhai]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Prov Key Lab Nanomat, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Peoples R China
  • [ 5 ] [Cai, Pingwei]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Peoples R China
  • [ 6 ] [Lu, Zhiwen]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Peoples R China
  • [ 7 ] [Mondal, Ritwik]Indian Inst Sci Educ & Res, Dept Chem, Pune 411008, Maharashtra, India
  • [ 8 ] [Thotiyl, Musthafa Ottakam]Indian Inst Sci Educ & Res, Dept Chem, Pune 411008, Maharashtra, India
  • [ 9 ] [Wen, Zhenhai]Fujian Sci & Technol Innovat Lab Optoelect Inform, Fuzhou 350108, Fujian, Peoples R China

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Source :

CHEMSUSCHEM

ISSN: 1864-5631

Year: 2022

8 . 4

JCR@2022

7 . 5 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:74

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 3

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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