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author:

Lu, Erjun (Lu, Erjun.) [1] | Zhang, Zhixiang (Zhang, Zhixiang.) [2] | Tao, Junqian (Tao, Junqian.) [3] | Yu, Zhiyang (Yu, Zhiyang.) [4] (Scholars:喻志阳) | Hou, Yidong (Hou, Yidong.) [5] (Scholars:侯乙东) | Zhang, Jinshui (Zhang, Jinshui.) [6] (Scholars:张金水)

Indexed by:

EI Scopus SCIE

Abstract:

The selective immobilization of noble metals right at the place where photogenerated electrons migrate through the photodeposition approach is a unique strategy to load cocatalysts on semiconductors for solar hydrogen production. However, a poor metal-semiconductor interaction is often formed, which not only hinders the interfacial charge transfer, but also results in the easy aggregation and shedding of cocatalysts during photocatalytic reactions. Herein, it is demonstrated that the photodeposited ultrafine metals, such as nanosized Au, can be well stabilized on TiO2 nanocrystallines without sintering by employing a sacrificial carbon coating annealing strategy to strengthen the metal-support interaction. Benefiting from the improved interfacial contact between Au and TiO2 for fast charge transfer and the well-preserved size-dependent catalytic behavior of Au nanoparticles toward hydrogen evolution reaction, the annealed Au/TiO2 exhibits a significant enhanced activity toward photocatalytic H-2 production with good durability.

Keyword:

cocatalyst-photocatalyst interaction interfacial engineering photocatalysis photodeposition

Community:

  • [ 1 ] [Lu, Erjun]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350108, Peoples R China
  • [ 2 ] [Zhang, Zhixiang]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350108, Peoples R China
  • [ 3 ] [Tao, Junqian]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350108, Peoples R China
  • [ 4 ] [Yu, Zhiyang]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350108, Peoples R China
  • [ 5 ] [Hou, Yidong]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350108, Peoples R China
  • [ 6 ] [Zhang, Jinshui]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350108, Peoples R China

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Source :

CHEMISTRY-A EUROPEAN JOURNAL

ISSN: 0947-6539

Year: 2022

Issue: 56

Volume: 28

4 . 3

JCR@2022

3 . 9 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:74

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 5

SCOPUS Cited Count: 6

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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