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author:

Xiao, Ni (Xiao, Ni.) [1] | Chen, Yinan (Chen, Yinan.) [2] | Weng, Wei (Weng, Wei.) [3] (Scholars:翁威) | Chi, Xiaopeng (Chi, Xiaopeng.) [4] (Scholars:迟晓鹏) | Chen, Hang (Chen, Hang.) [5] | Tang, Ding (Tang, Ding.) [6] | Zhong, Shuiping (Zhong, Shuiping.) [7] (Scholars:衷水平)

Indexed by:

Scopus SCIE

Abstract:

The controllable preparation of silver nanowires (AgNWs) with a high aspect ratio is key for enabling their applications on a large scale. Herein, the aspect ratio regulation of AgNWs mediated by halogen ion composition in ethylene glycol system was systematically investigated and the size evolution mechanism is elaborately understood. The co-addition of Br- and Cl- results in AgNWs with the highest aspect ratio of 1031. The surface physicochemical analysis of AgNWs and the density functional theory calculations indicate that the co-addition of Br- and Cl- contributes to the much-enhanced preferential growth of the Ag(111) crystal plane. At the same time, when Cl- and Br- coexist in the solution, the growth of the Ag(100) crystal plane on the AgNWs was restrained compared with that in the single Cl- system. Resultantly, the enhanced growth of Ag(111) and the inhibited growth of Ag(100) contribute to the formation of AgNWs with a higher aspect ratio in the Cl-Br mixed solution. The results can provide new insights for understanding the morphology and size evolution during the AgNWs preparation in ethylene glycol system.

Keyword:

aspect ratio density functional theory halogen ions silver nanowires surface adsorption

Community:

  • [ 1 ] [Xiao, Ni]Fuzhou Univ, Sch Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 2 ] [Chen, Yinan]Fuzhou Univ, Zijin Sch Geol & Min, Fuzhou 350108, Peoples R China
  • [ 3 ] [Weng, Wei]Fuzhou Univ, Zijin Sch Geol & Min, Fuzhou 350108, Peoples R China
  • [ 4 ] [Chi, Xiaopeng]Fuzhou Univ, Zijin Sch Geol & Min, Fuzhou 350108, Peoples R China
  • [ 5 ] [Zhong, Shuiping]Fuzhou Univ, Zijin Sch Geol & Min, Fuzhou 350108, Peoples R China
  • [ 6 ] [Weng, Wei]Fuzhou Univ, Fujian Key Lab Green Extract & High Value Utiliza, Fuzhou 350108, Peoples R China
  • [ 7 ] [Chi, Xiaopeng]Fuzhou Univ, Fujian Key Lab Green Extract & High Value Utiliza, Fuzhou 350108, Peoples R China
  • [ 8 ] [Zhong, Shuiping]Fuzhou Univ, Fujian Key Lab Green Extract & High Value Utiliza, Fuzhou 350108, Peoples R China
  • [ 9 ] [Chen, Hang]Zijin Min Grp Co Ltd, Shanghang 364200, Peoples R China
  • [ 10 ] [Tang, Ding]Zijin Min Grp Co Ltd, Shanghang 364200, Peoples R China
  • [ 11 ] [Zhong, Shuiping]Zijin Min Grp Co Ltd, Shanghang 364200, Peoples R China
  • [ 12 ] [Chen, Hang]State Key Lab Comprehens Utilizat Low Grade Refra, Shanghang 364200, Peoples R China
  • [ 13 ] [Tang, Ding]State Key Lab Comprehens Utilizat Low Grade Refra, Shanghang 364200, Peoples R China
  • [ 14 ] [Zhong, Shuiping]State Key Lab Comprehens Utilizat Low Grade Refra, Shanghang 364200, Peoples R China

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Source :

NANOMATERIALS

ISSN: 2079-4991

Year: 2022

Issue: 15

Volume: 12

5 . 3

JCR@2022

4 . 4 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:91

JCR Journal Grade:1

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 10

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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