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Due to the high photoinduced charge seperations, donor-acceptor (D-A) conjugated heptazine polymers containing fluorene donors have attracted much attention for their high photocatalytic degradations towards organic pollutants. To have an insight into the impact of the electron-donating ability of the donor moieties, herein three D-A conjugated heptazine polymers containing fluorene-like donors with different heteroatoms (dibenzofuran, carbazole, dibenzothiophene, named as CHP-O, CHP-N and CHP-S, respectively) have been synthesized through reversible Friedel-Crafts reactions. Interestingly, the photocatalytic evaluations reveal that all three compounds exhibit an exceptional photocatalytic reduction activity towards hexavalent chromium (Cr(VI)) with the conversion rates of 97%, 95% and 90% for CHP-O, CHP-N and CHP-S, respectively, upon the visible-light irradiation, which is attributed to the narrow band gap and high charge transfer efficiency in the crystalline conjugated systems.
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MATERIALS TODAY COMMUNICATIONS
ISSN: 2352-4928
Year: 2022
Volume: 31
3 . 8
JCR@2022
3 . 7 0 0
JCR@2023
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:91
JCR Journal Grade:2
CAS Journal Grade:4
Cited Count:
WoS CC Cited Count: 3
SCOPUS Cited Count: 3
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 2
Affiliated Colleges: