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author:

Li, Zhen (Li, Zhen.) [1] | Jiang, Zi-Jian (Jiang, Zi-Jian.) [2] | Zheng, Jun-Feng (Zheng, Jun-Feng.) [3] | Lin, Mei-Jin (Lin, Mei-Jin.) [4] (Scholars:林梅金)

Indexed by:

EI Scopus SCIE

Abstract:

Due to the high photoinduced charge seperations, donor-acceptor (D-A) conjugated heptazine polymers containing fluorene donors have attracted much attention for their high photocatalytic degradations towards organic pollutants. To have an insight into the impact of the electron-donating ability of the donor moieties, herein three D-A conjugated heptazine polymers containing fluorene-like donors with different heteroatoms (dibenzofuran, carbazole, dibenzothiophene, named as CHP-O, CHP-N and CHP-S, respectively) have been synthesized through reversible Friedel-Crafts reactions. Interestingly, the photocatalytic evaluations reveal that all three compounds exhibit an exceptional photocatalytic reduction activity towards hexavalent chromium (Cr(VI)) with the conversion rates of 97%, 95% and 90% for CHP-O, CHP-N and CHP-S, respectively, upon the visible-light irradiation, which is attributed to the narrow band gap and high charge transfer efficiency in the crystalline conjugated systems.

Keyword:

Conjugated polymers Cr(VI) reduction Donor-Acceptor Heptazines Heteroatom engineering

Community:

  • [ 1 ] [Li, Zhen]Fuzhou Univ, Coll Chem, Fujian Prov Key Lab Adv Inorgan Oxygenated Mat, Fuzhou 350116, Peoples R China
  • [ 2 ] [Jiang, Zi-Jian]Fuzhou Univ, Coll Chem, Fujian Prov Key Lab Adv Inorgan Oxygenated Mat, Fuzhou 350116, Peoples R China
  • [ 3 ] [Zheng, Jun-Feng]Fuzhou Univ, Coll Chem, Fujian Prov Key Lab Adv Inorgan Oxygenated Mat, Fuzhou 350116, Peoples R China
  • [ 4 ] [Lin, Mei-Jin]Fuzhou Univ, Coll Chem, Fujian Prov Key Lab Adv Inorgan Oxygenated Mat, Fuzhou 350116, Peoples R China
  • [ 5 ] [Lin, Mei-Jin]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350116, Peoples R China

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Source :

MATERIALS TODAY COMMUNICATIONS

ISSN: 2352-4928

Year: 2022

Volume: 31

3 . 8

JCR@2022

3 . 7 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:91

JCR Journal Grade:2

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 3

SCOPUS Cited Count: 3

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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