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The conversion of solar energy in a wide spectrum region to clean fuel, H-2, remains a challenge in the field of photocatalysis. Herein, plasmonic TiN nanobelts, as a novel cocatalyst, were coupled with CdS nanoparticles to construct a 0D/1D CdS/TiN heterojunction. Utilization of the localized surface plasmon resonance (LSPR) effect generated from TiN nanobelts was effective in promoting light absorption in the near-infrared region, accelerating charge separation, and generating hot electrons, which can effectively improve the photocatalytic H-2 generation activity of the 0D/1D CdS/TiN heterojunction over a wide spectral range. Furthermore, owing to the high metallicity and low work function, an ohmic-junction was formed between the CdS and TiN, favoring the transfer of hot electrons generated from TiN nanobelts the CdS nanoparticles, followed by the reaction with water to generate H-2. Consequently, the 0D/1D CdS/TiN heterojunction demonstrated H-2 generation activity even under light irradiation at 760 nm, while the pure CdS and Pt nanoparticles modified CdS presented no activity. This work opens a new insight into coupling plasmonic cocatalysts to realize full spectrum H-2 production. (C) 2022 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.
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JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
ISSN: 1005-0302
CN: 21-1315/TG
Year: 2022
Volume: 116
Page: 1-10
1 0 . 9
JCR@2022
1 1 . 2 0 0
JCR@2023
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:91
JCR Journal Grade:1
CAS Journal Grade:1
Cited Count:
WoS CC Cited Count: 47
SCOPUS Cited Count: 47
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 2
Affiliated Colleges: