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author:

He, Xudong (He, Xudong.) [1] | Liu, Qinqin (Liu, Qinqin.) [2] | Xu, Difa (Xu, Difa.) [3] | Wang, Lele (Wang, Lele.) [4] | Tang, Hua (Tang, Hua.) [5]

Indexed by:

EI Scopus SCIE CSCD

Abstract:

The conversion of solar energy in a wide spectrum region to clean fuel, H-2, remains a challenge in the field of photocatalysis. Herein, plasmonic TiN nanobelts, as a novel cocatalyst, were coupled with CdS nanoparticles to construct a 0D/1D CdS/TiN heterojunction. Utilization of the localized surface plasmon resonance (LSPR) effect generated from TiN nanobelts was effective in promoting light absorption in the near-infrared region, accelerating charge separation, and generating hot electrons, which can effectively improve the photocatalytic H-2 generation activity of the 0D/1D CdS/TiN heterojunction over a wide spectral range. Furthermore, owing to the high metallicity and low work function, an ohmic-junction was formed between the CdS and TiN, favoring the transfer of hot electrons generated from TiN nanobelts the CdS nanoparticles, followed by the reaction with water to generate H-2. Consequently, the 0D/1D CdS/TiN heterojunction demonstrated H-2 generation activity even under light irradiation at 760 nm, while the pure CdS and Pt nanoparticles modified CdS presented no activity. This work opens a new insight into coupling plasmonic cocatalysts to realize full spectrum H-2 production. (C) 2022 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.

Keyword:

CdS LSPR Photocatalytic H-2 generation Plasmon TiN

Community:

  • [ 1 ] [He, Xudong]Jiangsu Univ, Sch Mat Sci & Engn, Zhenjiang 212013, Jiangsu, Peoples R China
  • [ 2 ] [Liu, Qinqin]Jiangsu Univ, Sch Mat Sci & Engn, Zhenjiang 212013, Jiangsu, Peoples R China
  • [ 3 ] [Wang, Lele]Jiangsu Univ, Sch Mat Sci & Engn, Zhenjiang 212013, Jiangsu, Peoples R China
  • [ 4 ] [Tang, Hua]Qingdao Univ, Sch Environm Sci & Engn, Qingdao 266071, Peoples R China
  • [ 5 ] [Liu, Qinqin]Changsha Univ, Hunan Key Lab Appl Environm Photocatalysis, Changsha 410022, Peoples R China
  • [ 6 ] [Xu, Difa]Changsha Univ, Hunan Key Lab Appl Environm Photocatalysis, Changsha 410022, Peoples R China
  • [ 7 ] [Wang, Lele]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350108, Peoples R China

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Source :

JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY

ISSN: 1005-0302

CN: 21-1315/TG

Year: 2022

Volume: 116

Page: 1-10

1 0 . 9

JCR@2022

1 1 . 2 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:91

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 47

SCOPUS Cited Count: 47

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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