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author:

Shao YeQing (Shao YeQing.) [1] | Xie YongHui (Xie YongHui.) [2] | Yang Yang (Yang Yang.) [3] | Cao JiaQi (Cao JiaQi.) [4] | Li XiuWan (Li XiuWan.) [5] | Li WangYang (Li WangYang.) [6] | Zhang QiaoLi (Zhang QiaoLi.) [7] | Cheng ShouLin (Cheng ShouLin.) [8] | Cheng ShuYing (Cheng ShuYing.) [9] (Scholars:程树英) | Wang XingHui (Wang XingHui.) [10] (Scholars:王星辉)

Indexed by:

EI Scopus SCIE CSCD

Abstract:

Lithium metal anodes (LMAs) are considered as the promising alternatives for next-generation high energy density batteries, but are still hampered by the severe growth of uncontrollable lithium dendrites. The growth of lithium dendrites induces poor cycling lifespan and serious safety concerns, dragging lithium metal batteries out of practical applications. We designed a bilayer carbon-based structure covered with Co/C nanosheets and vertical graphene sheets (VGS). The enormous specific surface area and uniformly distributed Co nanoparticles of the CC@Co/C-VGS host are derived from its unique design, which can reduce local current density and nucleation overpotential, resulting in a dendrite-free morphology and exceptional cycling stability. Symmetric cells exhibit over 400 cycles (800 h) at a high current density/capacity of 10 mA cm(-2)/10 mA h cm(-2). Full cells using LiFePO4 as the cathode have an enhanced rate capability and a prolonged lifespan, reaching 90 mA h g(-1) after 1000 cycles at 2 C with 73.5% capacity retention. This unique design sheds light on developing high-performance LMAs.

Keyword:

bilayer carbon structure graphene lithiophilic material lithium metal anode MOF

Community:

  • [ 1 ] [Shao YeQing]Fuzhou Univ, Inst Micronano Devices & Solar Cells, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China
  • [ 2 ] [Xie YongHui]Fuzhou Univ, Inst Micronano Devices & Solar Cells, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China
  • [ 3 ] [Yang Yang]Fuzhou Univ, Inst Micronano Devices & Solar Cells, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China
  • [ 4 ] [Cao JiaQi]Fuzhou Univ, Inst Micronano Devices & Solar Cells, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China
  • [ 5 ] [Li WangYang]Fuzhou Univ, Inst Micronano Devices & Solar Cells, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China
  • [ 6 ] [Zhang QiaoLi]Fuzhou Univ, Inst Micronano Devices & Solar Cells, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China
  • [ 7 ] [Cheng ShouLin]Fuzhou Univ, Inst Micronano Devices & Solar Cells, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China
  • [ 8 ] [Cheng ShuYing]Fuzhou Univ, Inst Micronano Devices & Solar Cells, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China
  • [ 9 ] [Wang XingHui]Fuzhou Univ, Inst Micronano Devices & Solar Cells, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China
  • [ 10 ] [Shao YeQing]Fujian Sci & Technol Innovat Lab Optoelect Inform, Fuzhou 350108, Peoples R China
  • [ 11 ] [Wang XingHui]Fujian Sci & Technol Innovat Lab Optoelect Inform, Fuzhou 350108, Peoples R China
  • [ 12 ] [Li XiuWan]Huaqiao Univ, Coll Informat Sci & Engn, Fujian Prov Key Lab Light Propagat & Transformat, Xiamen 361000, Peoples R China
  • [ 13 ] [Cheng ShuYing]Jiangsu Collaborat Innovat Ctr Photovolta Sci & E, Changzhou 213000, Peoples R China
  • [ 14 ] [Wang XingHui]Jiangsu Collaborat Innovat Ctr Photovolta Sci & E, Changzhou 213000, Peoples R China
  • [ 15 ] [Cheng ShuYing]Fuzhou Univ, Fujian Key Lab Electrochem Energy Storage Mat, Fuzhou 350002, Peoples R China

Reprint 's Address:

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Source :

SCIENCE CHINA-TECHNOLOGICAL SCIENCES

ISSN: 1674-7321

CN: 11-5845/TH

Year: 2022

Issue: 7

Volume: 65

Page: 1558-1566

4 . 6

JCR@2022

4 . 4 0 0

JCR@2023

ESI Discipline: ENGINEERING;

ESI HC Threshold:66

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 5

SCOPUS Cited Count: 5

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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