Synthesis of 2,3-Bis(trifluoromethylseleno) Indoles through an Oxidative Copper-Mediated Domino Reaction - Details

author：

Wang, Hui (Wang, Hui.) ^[1] | Yao, Yunfei (Yao, Yunfei.) ^[2] | Zhang, Zipeng (Zhang, Zipeng.) ^[3] | Huang, Yangjie (Huang, Yangjie.) ^[4] | Weng, Zhiqiang (Weng, Zhiqiang.) ^[5]

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Abstract：

An　oxidative　copper-mediated　double　trifluoromethylselenolation　of　terminal　2-alkynylanilines　using　[(bpy)CuSeCF3]2is　reported,　providing　a　moderately　efficient　and　convenient　approach　to　2,3-bis(trifluoromethylseleno)indoles.　Mechanistic　studies　show　that　a　cascade　sequence　of　oxidation,　trifluoromethylselenolation,　5-endo-dig　cyclization,　and　elimination　is　involved　in　this　transformation.　©　2022　American　Chemical　Society.　All　rights　reserved.

Keyword：

Copper Reaction kinetics

Community：

[ 1 ] [Wang, Hui]Fujian Engineering Research Center of New Chinese Lacquer Material, Ocean College, Minjiang University, Fuzhou; 350108, China
[ 2 ] [Wang, Hui]Key Laboratory of Molecule Synthesis and Function Discovery, Fujian Provincial Key Laboratory of Electrochemical Energy Storage Materials, College of Chemistry, Fuzhou University, Fuzhou; 350108, China
[ 3 ] [Yao, Yunfei]Key Laboratory of Molecule Synthesis and Function Discovery, Fujian Provincial Key Laboratory of Electrochemical Energy Storage Materials, College of Chemistry, Fuzhou University, Fuzhou; 350108, China
[ 4 ] [Zhang, Zipeng]Key Laboratory of Molecule Synthesis and Function Discovery, Fujian Provincial Key Laboratory of Electrochemical Energy Storage Materials, College of Chemistry, Fuzhou University, Fuzhou; 350108, China
[ 5 ] [Huang, Yangjie]Fujian Engineering Research Center of New Chinese Lacquer Material, Ocean College, Minjiang University, Fuzhou; 350108, China
[ 6 ] [Weng, Zhiqiang]Fujian Engineering Research Center of New Chinese Lacquer Material, Ocean College, Minjiang University, Fuzhou; 350108, China
[ 7 ] [Weng, Zhiqiang]Key Laboratory of Molecule Synthesis and Function Discovery, Fujian Provincial Key Laboratory of Electrochemical Energy Storage Materials, College of Chemistry, Fuzhou University, Fuzhou; 350108, China

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Source ：

Journal of Organic Chemistry

ISSN： 0022-3263

Year： 2022

Issue： 5

Volume： 87

Page： 3605-3612

3 . 6

JCR@2022

3 . 4 0 0

JCR@2023

ESI HC Threshold：74

JCR Journal Grade：1

CAS Journal Grade：2

Cited Count：

WoS CC Cited Count： 0

SCOPUS Cited Count： 8

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 0

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