The　effect　of　phytosterol　organogelators　(β-sitosterol　:　γ-oryzanol=2　:　3,　m　:　m)　on　the　network　structure　and　oxidation　characteristics　of　soybean　oil　oleogels　were　studied.　The　results　showed　that　when　the　addition　amount　of　phytosterol　organogelators　was　within　the　range　of　2%　to　10%,　the　storage　modulus　(G＇)　of　soybean　oil　oleogels　of　6%　was　always　higher　than　loss　modulus　(G＇＇),　which　indicated　that　the　system　had　formed　a　stable　solid-like　gel　structure.　Polarized　light　microscopy　showed　that　6%　oleogels　appeared　a　regular　and　compact　aggregation　state　after　stored　at　45　for　10　days,　with　a　peroxide　value　of　15.59　mmol/kg,　a　malondialdehyde　content　of　1.49　mg/kg,　and　a　headspace　oxygen　consumption　of　24.19%,　showed　the　best　oxidation　stability.　2%　to　10%　of　β-sitosterol　or　γ-oryzanol　was　added　to　soybean　oil　respectively,　the　headspace　oxygen　consumption　of　the　sample　showed　that　β-sitosterol　had　an　anti-oxidant　effect,　and　γ-oryzanol　had　a　pro-oxidant　effect.　After　heated　at　180　for　2.5　hours,　the　headspace　oxygen　consumption　of　6%　phytosterol　oleogels　was　5.00%　lower　than　the　control,　showed　a　good　thermal　oxidation　stability.　Meanwhile,　both　Rao　and　Rad　acquired　from　1H　NMR　spectra　had　a　good　positive　correlation　with　the　total　oxidation　value　of　phytosterol　oleogels　during　the　thermal　oxidation　at　70　.　©　2022,　Editorial　Office　of　Journal　of　CIFST.　All　right　reserved.