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author:

Gao, Xiangqi (Gao, Xiangqi.) [1] | Fang, Gaoyang (Fang, Gaoyang.) [2] | Wang, Yan (Wang, Yan.) [3] | Zhu, Zhaojie (Zhu, Zhaojie.) [4] | You, Zhenyu (You, Zhenyu.) [5] | Li, Jianfu (Li, Jianfu.) [6] | sun, Yijian (sun, Yijian.) [7] | Tu, Chaoyang (Tu, Chaoyang.) [8]

Indexed by:

EI

Abstract:

1 at% Dy3+: CaF2 and 1 at% Dy3+/5 at% Y3+: CaF2 crystals were grown by Bridgman method. Absorptions, visible and mid-infrared emissions, and fluorescence decay curves were measured. By applying Judd-Ofelt (J-O) theory, for Dy3+/Y3+: CaF2 crystal stronger oscillator strength and radiation transition probability were derived. The effect of Y3+ ions incorporation into CaF2 crystals on the light emission of Dy3+ ions was discussed. Co-doped Y3+ ions can destroy Dy clusters, cripple the concentration quenching effect, and enhance the yellow and mid-infrared fluorescence intensity. The yellow fluorescence intensity of Dy3+/Y3+: CaF2 is ~ 70 times higher than that of Dy3+: CaF2 crystal. The local structure of Dy3+ ions was analyzed, and co-doping Y3+ can increase the quantity of tetragonal Dy clusters. In Dy3+/Y3+: CaF2 crystal, the tetragonal Dy clusters occupy the dominant position, and the fluorescence lifetime (τf) is relatively short. It can be concluded that Dy3+: CaF2 and Dy3+/Y3+: CaF2 crystals are expected to achieve yellow and mid-infrared laser output simultaneously. © 2020 Elsevier B.V.

Keyword:

Calcium fluoride Crystal growth from melt Crystals Dysprosium Fluorescence Fluorine compounds Fluorspar Infrared devices Ions Judd-Ofelt theory Optical parametric oscillators Yttrium compounds

Community:

  • [ 1 ] [Gao, Xiangqi]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou City; Fujian Province; 350002, China
  • [ 2 ] [Gao, Xiangqi]College of Chemistry and Materials Science, Fujian Normal University, Fuzhou City; Fujian Province; 350007, China
  • [ 3 ] [Gao, Xiangqi]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China (Mindu Innovation Laboratory), Fuzhou; Fujian; 350108, China
  • [ 4 ] [Fang, Gaoyang]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou City; Fujian Province; 350002, China
  • [ 5 ] [Fang, Gaoyang]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China (Mindu Innovation Laboratory), Fuzhou; Fujian; 350108, China
  • [ 6 ] [Fang, Gaoyang]College of Chemistry, Fuzhou University, Fuzhou City; Fujian Province; 350116, China
  • [ 7 ] [Wang, Yan]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou City; Fujian Province; 350002, China
  • [ 8 ] [Wang, Yan]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China (Mindu Innovation Laboratory), Fuzhou; Fujian; 350108, China
  • [ 9 ] [Zhu, Zhaojie]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou City; Fujian Province; 350002, China
  • [ 10 ] [Zhu, Zhaojie]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China (Mindu Innovation Laboratory), Fuzhou; Fujian; 350108, China
  • [ 11 ] [You, Zhenyu]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou City; Fujian Province; 350002, China
  • [ 12 ] [You, Zhenyu]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China (Mindu Innovation Laboratory), Fuzhou; Fujian; 350108, China
  • [ 13 ] [Li, Jianfu]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou City; Fujian Province; 350002, China
  • [ 14 ] [Li, Jianfu]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China (Mindu Innovation Laboratory), Fuzhou; Fujian; 350108, China
  • [ 15 ] [sun, Yijian]Faculty of Materials Metallurgy and Chemical, Jiangxi University of Science and Technology, Ganzhou; Jiangxi; 341000, China
  • [ 16 ] [Tu, Chaoyang]Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou City; Fujian Province; 350002, China
  • [ 17 ] [Tu, Chaoyang]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China (Mindu Innovation Laboratory), Fuzhou; Fujian; 350108, China

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Source :

Journal of Alloys and Compounds

ISSN: 0925-8388

Year: 2021

Volume: 856

6 . 3 7 1

JCR@2021

5 . 8 0 0

JCR@2023

ESI HC Threshold:142

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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