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[期刊论文]

Recent Advances in Palladium-Catalyzed Bridging C-H Activation by Using Alkenes, Alkynes or Diazo Compounds as Bridging Reagents

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author:

Zhang, Fulin (Zhang, Fulin.) [1] | Xin, Luoting (Xin, Luoting.) [2] | Yu, Yinghua (Yu, Yinghua.) [3] | Unfold

Indexed by:

EI

Abstract:

Transition-metal-catalyzed direct inert C-H bond functionalization has attracted much attention over the past decades. However, because of the high strain energy of the suspected palladacycle generated via C-H bond palladation, direct functionalization of a C-H bond less than a three-bond distance from a catalyst center is highly challenging. In this short review, we summarize the advances on palladium-catalyzed bridging C-H activation, in which an inert proximal C-H bond palladation is promoted by the elementary step of migratory insertion of an alkene, an alkyne or a metal carbene intermediate. 1 Introduction 2 Palladium-Catalyzed Alkene Bridging C-H Activation 2.1 Intramolecular Reactions 2.2 Intermolecular Reactions 3 Palladium-Catalyzed Alkyne Bridging C-H Activation 3.1 Intermolecular Reactions 3.2 Intramolecular Reactions 4 Palladium-Catalyzed Carbene Bridging C-H Activation 5 Conclusion and Outlook. © 2020 BMJ Publishing Group. All rights reserved.

Keyword:

Activation analysis Catalysis Chemical activation Olefins Palladium Reagents Strain energy Transition metals

Community:

  • [ 1 ] [Zhang, Fulin]Key Laboratory for Molecule Synthesis and Function Discovery (Fujian Province University), College of Chemistry, Fuzhou University, Fuzhou; 350116, China
  • [ 2 ] [Xin, Luoting]Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Center for Excellence in Molecular Synthesis, Fujian Institute of Research on the Structure of Matter, Fujian College, University of Chinese Academy of Sciences, Chinese Academy of Sciences, Fuzhou, Fujian; 350002, China
  • [ 3 ] [Yu, Yinghua]Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Center for Excellence in Molecular Synthesis, Fujian Institute of Research on the Structure of Matter, Fujian College, University of Chinese Academy of Sciences, Chinese Academy of Sciences, Fuzhou, Fujian; 350002, China
  • [ 4 ] [Liao, Saihu]Key Laboratory for Molecule Synthesis and Function Discovery (Fujian Province University), College of Chemistry, Fuzhou University, Fuzhou; 350116, China
  • [ 5 ] [Huang, Xueliang]Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Center for Excellence in Molecular Synthesis, Fujian Institute of Research on the Structure of Matter, Fujian College, University of Chinese Academy of Sciences, Chinese Academy of Sciences, Fuzhou, Fujian; 350002, China

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Source :

Synthesis (Germany)

ISSN: 0039-7881

Year: 2021

Issue: 2

Volume: 53

Page: 238-254

2 . 9 6 9

JCR@2021

2 . 2 0 0

JCR@2023

ESI HC Threshold:117

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count:

30 Days PV: 0

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