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author:

Lin, Ju (Lin, Ju.) [1] (Scholars:林驹) | Zhang, Ji-Yu (Zhang, Ji-Yu.) [2] (Scholars:张济宇) | Zhong, Xue-Qing (Zhong, Xue-Qing.) [3]

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EI Scopus PKU CSCD

Abstract:

Catalytic steam gasification kinetics of Fujian Youxi anthracite using viscose liquor as catalyst was investigated in an isothermal thermo-gravimetric analyzer under ambient pressure. Coal conversions versus reaction time with different viscose liquor concentrations (0~12% NaOH) were measured at the temperature range from 850C to 950C. The research shows that the viscose liquor can greatly improve the gasification rate and carbon conversion. The Loading Saturation Level (LSL) of the viscose liquor within the experimental conditions was also determined. The catalytic steam gasification reaction can be well fitted by a shrinking-core model (SCM) and the reaction rate constants are obtained. The kinetic analysis indicates that the catalytic gasification exhibits a prominent compensation effect between the activation energy and the pre-exponential factor. The kinetic equation including the compensation effects for the catalytic steam gasification of Fujian Youxi anthracite using viscose liquor as catalyst is presented.

Keyword:

Activation analysis Activation energy Anthracite Catalysts Gasification Integral equations Kinetic parameters Kinetics Rate constants Sodium hydroxide Steam Thermogravimetric analysis

Community:

  • [ 1 ] [Lin, Ju]Institute of Chemical Engineering and Technology, Fuzhou University, Fuzhou 350002, China
  • [ 2 ] [Zhang, Ji-Yu]Institute of Chemical Engineering and Technology, Fuzhou University, Fuzhou 350002, China
  • [ 3 ] [Zhong, Xue-Qing]Institute of Chemical Engineering and Technology, Fuzhou University, Fuzhou 350002, China

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Source :

Journal of Fuel Chemistry and Technology

ISSN: 0253-2409

Year: 2009

Issue: 4

Volume: 37

Page: 398-404

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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