A facile method for Rh-catalyzed decarbonylativeortho-C-H alkylation of (hetero)arenes with alkyl carboxylic acids - Details

author：

Tian, Yiqiang (Tian, Yiqiang.) ^[1] | Liu, Xiaojie (Liu, Xiaojie.) ^[2] | He, Bangyue (He, Bangyue.) ^[3] | Ren, Yuxi (Ren, Yuxi.) ^[4] | Su, Weiping (Su, Weiping.) ^[5]

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Abstract：

A　facile　and　effective　method　for　Rh-catalyzed　directortho-alkylation　of　C-H　bonds　in　(hetero)arenes　with　commercially　available　carboxylic　acids　has　been　developed.　This　strategy　was　initiated　byin　situconversion　of　carboxylic　acids　to　anhydrides　which,　without　isolation,　underwent　Rh-catalyzed　direct　decarbonylative　cross-coupling　of　aryl　carboxamides　containing　8-aminoquinoline.　The　reaction　proceeds　with　high　regioselectivity　and　exhibits　a　broad　substrate　scope　as　well　as　functional　group　tolerance.　©　The　Royal　Society　of　Chemistry　2021.

Keyword：

Alkylation Aromatic hydrocarbons Carboxylic acids Catalysis Rhodium compounds

Community：

[ 1 ] [Tian, Yiqiang]College of Chemistry, Fuzhou University, Fuzhou; 350116, China
[ 2 ] [Tian, Yiqiang]State Key Laboratory of Structural Chemistry, Center for Excellence in Molecular Synthesis, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou; 350002, China
[ 3 ] [Liu, Xiaojie]College of Chemistry, Fuzhou University, Fuzhou; 350116, China
[ 4 ] [Liu, Xiaojie]State Key Laboratory of Structural Chemistry, Center for Excellence in Molecular Synthesis, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou; 350002, China
[ 5 ] [He, Bangyue]State Key Laboratory of Structural Chemistry, Center for Excellence in Molecular Synthesis, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou; 350002, China
[ 6 ] [Ren, Yuxi]State Key Laboratory of Structural Chemistry, Center for Excellence in Molecular Synthesis, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou; 350002, China
[ 7 ] [Su, Weiping]State Key Laboratory of Structural Chemistry, Center for Excellence in Molecular Synthesis, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou; 350002, China

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Source ：

RSC Advances

Year： 2021

Issue： 32

Volume： 11

Page： 19827-19831

4 . 0 3 6

JCR@2021

3 . 9 0 0

JCR@2023

ESI HC Threshold：117

JCR Journal Grade：2

CAS Journal Grade：4

Cited Count：

WoS CC Cited Count：

SCOPUS Cited Count： 1

ESI Highly Cited Papers on the List： 0 Unfold All

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Chinese Cited Count：

30 Days PV： 2

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