• Complex
  • Title
  • Keyword
  • Abstract
  • Scholars
  • Journal
  • ISSN
  • Conference
成果搜索

[期刊论文]

Construction of a 2D/2D WO3/LaTiO2N Direct Z-Scheme Photocatalyst for Enhanced CO2 Reduction Performance Under Visible Light

Share
Edit Delete 报错

author:

Lin, Nansong (Lin, Nansong.) [1] | Lin, Yuan (Lin, Yuan.) [2] | Qian, Xinjia (Qian, Xinjia.) [3] | Unfold

Indexed by:

EI SCIE

Abstract:

It remains a challenge to search for semiconductor photocatalysts for the overall conversion of carbon dioxide (CO2) with H2O to hydrocarbons. Herein, two-dimensional (2D) WO3 nanosheets were loaded on 2D LaTiO2N microplates to construct a direct Z-scheme photocatalytic system to realize the overall conversion of gas-phase CO2 and H2O without any noble metal cocatalysts or sacrificial reagents under visible light. The optimal performance has been achieved by a WO3/LaTiO2N composite, and the yields of CO and CH4 of 2.21 and 0.36 mu mol g(-1) h(-1) are obtained by reducing CO2, respectively. The total utilized photoelectron number (UPN) has reached 7.3 mu mol g(-1) h(-1), which is approximately 4.3 and 8.7 times higher than that of the pristine LaTiO2N and WO3, respectively. The improved photocatalytic activity for CO2 reduction can be due to the promoted charge separation by the formation of a Z-scheme heterojunction between LaTiO2N and WO3. Moreover, the short charge transfer distance and large contact interface between 2D WO3 and 2D LaTiO2N further accelerate the transfer of photogenerated carriers. This study is anticipated to develop novel perspectives for the reasonable development and preparation of high-efficient 2D/2D Z-scheme photocatalysts for CO2 reduction.

Keyword:

2D/2D Z-scheme composite LaTiO2N photocatalytic CO2 reduction WO3

Community:

  • [ 1 ] [Lin, Nansong]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Peoples R China
  • [ 2 ] [Lin, Yuan]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Peoples R China
  • [ 3 ] [Qian, Xinjia]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Peoples R China
  • [ 4 ] [Wang, Xuxu]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Peoples R China
  • [ 5 ] [Su, Wenyue]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Peoples R China

Reprint 's Address:

  • 苏文悦

    [Su, Wenyue]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Peoples R China

Show more details

Source :

ACS SUSTAINABLE CHEMISTRY & ENGINEERING

ISSN: 2168-0485

Year: 2021

Issue: 40

Volume: 9

Page: 13686-13694

9 . 2 2 4

JCR@2021

7 . 1 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:117

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 46

SCOPUS Cited Count: 51

30 Days PV: 0

Online/Total:164/10289117
Address:FZU Library(No.2 Xuyuan Road, Fuzhou, Fujian, PRC Post Code:350116) Contact Us:0591-22865326
Copyright:FZU Library Technical Support:Beijing Aegean Software Co., Ltd. 闽ICP备05005463号-1