TiO2　is　considered　as　a　potential　anode　with　the　advantages　of　stable　structure　and　high　safety.　However,　the　large-scale　application　of　TiO2　is　restricted　due　to　its　low　electronic　conductivity　and　sluggish　Na+　diffusion.　In　the　present　work,　anatase　and　TiO2-B　dual-phase　TiO2　hollow　microspheres　(TiO2-MS)　were　designed　through　a　universal　hydrothermal　reaction.　These　microspheres　were　composed　of　nanosheets,　and　the　nanosheets　were　consisted　of　small　nanoparticles.　Benefitting　from　the　synergistic　effect　of　dual-phase　TiO2　nanoparticles　and　hierarchical　structure,　the　TiO2-MS　can　not　only　buffer　the　volume　changes　during　Na+　intercalation/deintercalation　process,　but　also　provide　the　contact　space　for　electrolyte　-　electrode.　As　a　result,　the　TiO2-MS　anode　delivered　a　distinguished　sodium　storage　performance,　maintained　240　mA　h　g(-1)　at　2C　(1C　=　168　mA　g(-1))　after　150　cycles.　Even　the　current　density　was　increased　to　20C,　a　capacity　of　159.7　mA　h　g(-1)　can　still　be　maintained　after　5000　cycles.