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Abstract:
Recently, scientists have reported a range of chiral fluorescence materials or chiral composites that can emit circularly polarized luminescence. Herein, two achiral metal-organic colloidal solutions were studied, showing active circularly polarized luminescence, which is observed in vortex stirring. The absolute values for g(lum) are 0.05 and 0.03 and the plus or minus sign of g(lum) depends on the colloidal structure and stirring direction, which make the property easy to manipulate. Further, the host-guest interaction study suggests both electrostatic interactions and coordination bonding may influence the chiroptical property from the colloidal solution to the guest molecule. Rhodamine 6G and its carboxylic acid derivative exhibit good quantum yields and acceptable g(lum) values in the colloidal solution.
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CHEMISTRY-A EUROPEAN JOURNAL
ISSN: 0947-6539
Year: 2021
Issue: 22
Volume: 27
Page: 6760-6766
5 . 0 2
JCR@2021
3 . 9 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:117
JCR Journal Grade:2
CAS Journal Grade:3
Cited Count:
WoS CC Cited Count: 8
SCOPUS Cited Count: 8
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
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