Translated Title

Alkoxo-bridged Dinuclear Coppe(Ⅱ) Complex with Mixed Ligands: Synthesis,X-ray Crystal Structure and Theoretical Investigation

Translated Abstract

The　synthesis,　structural　characterization　and　theoretical　investigation　of　a　novel　alkoxo-bridged　dinuclear　copper(Ⅱ)　compound　has　been　described.　The　title　compound　has　the　formula　C22H28Cl2Cu2N8O11.　It　consists　of　dinuclear　units　with　bridging　methoxo　groups.　The　ligands　2-amino-pyridine　and　2-amino-6-hydroxyl-pyridine　are　linked　to　each　copper　via　the　pyridine　N　atoms　respectively,　providing　a　square　planar　CuN2O2　unit.　The　ClO4-　anions　in　the　title　compound　are　semi-coordinated　to　copper　ion　at　the　distance　of　0.265　83(4)　nm　(Cu-O　(ClO4-).　The　Cu-Cu　distances　within　the　dinuclear　units　are　0.299　79(9)　nm　with　Cu-O-Cu　angles　of　102.27(9)°.The　structures　are　stabilized　by　intramolecular　H-bonds　between　the　amino　hydrogen　atoms　and　oxygen　atoms.Based　on　crystal　data,　quantum　chemistry　calculation　on　DFT/B3LPY　level　was　used　to　reveal　the　electronic　structure　of　the　title　compound.　CCDC:　270807.

Translated Keyword

alkoxo-bridged
copper(Ⅱ) complex
mixed ligands complex
quantum chemistry calculation

Classification

O614.121

Type

Project Name

Project No.

Access Number

WF:perioarticalwjhxxb200603026

Language

Chinese

Corresponding s email

Author Info