Crystal and electronic structure of novel organic-inorganic hybrid coordination polymer {[C12H28N2][(Pb 3I8) (DMF)2]•2DMF}n - Details

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Abstract：

A　novel　organic-inorganic　hybrid　coordination　polymer　{[C　12H28N2]　[(Pb3I8)　(DMF)2]•2DMF}n　was　synthesized　by　self-assembling　method　and　characterized　by　IR,　UV/Vis　and　thermal　analysis.　The　crystal　structure　was　determined　by　X-ray　diffraction　analysis　and　its　quantum　chemical　calculation　was　performed　by　Gaussian03　program.　The　title　compound　consists　of　cations　([C12H28N2]2+)　and　anion　chains　([(Pb3I8)(DMF)22-]　n)　that　are　combined　by　static　attractive　forces　in　the　crystal.

Keyword：

Coordination polymer; Crystal structure; Organic-inorganic hybrid

Community：

[ 1 ] [Li, H.-H.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350002, China
[ 2 ] [Chen, Z.-R.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350002, China
[ 3 ] [Li, J.-Q.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350002, China
[ 4 ] [Huang, C.-C.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350002, China
[ 5 ] [Xiao, G.-C.]Center of Analysis and Measurement, Fuzhou University, Fuzhou 350002, China
[ 6 ] [Lian, Z.-X.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350002, China
[ 7 ] [Hu, X.-L.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350002, China

Reprint 's Address：

李浩宏
[Li, H.-H.]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350002, China

Email：

lihhfzu@tom.com

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Source ：

Acta Chimica Sinica

ISSN： 0567-7351

CN： 31-1320/O6

Year： 2005

Issue： 8

Volume： 63

Page： 697-702

0 . 8 4 5

JCR@2005

1 . 7 0 0

JCR@2023

ESI Discipline： CHEMISTRY;

JCR Journal Grade：3

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ESI Highly Cited Papers on the List： 0 Unfold All

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30 Days PV： 0

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化学学院本学院/部未明确归属的数据

福建省高校测试中心本学院/部未明确归属的数据

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