A pseudo-Keggin compound: Hydrothermal synthesis and crystal structure of (DETAH)(DETAH3)3[V18O42(PO 4)]·(PO4)·2H2O - Details

author：

Xiang, Y. (Xiang, Y..) ^[1] | Zhang, L.-W. (Zhang, L.-W..) ^[2] | Chen, W.-H. (Chen, W.-H..) ^[3] | Chen, J.-Z. (Chen, J.-Z..) ^[4] (Scholars：陈建中) | Zeng, Q.-X. (Zeng, Q.-X..) ^[5] (Scholars：曾庆新)

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Abstract：

The　novel　vanadophosphate　(DETAH)(DETAH3)3[V　18O42(PO4)]·(PO4)　·2H2O　has　been　synthesized　under　hydrothermal　conditions　and　its　structure　was　determined　by　single-crystal　X-ray　diffraction.　The　compound　crystallizes　in　monoclinic,　space　group　C2/c　with　a　=　23.857(3),　b　=　12.9619(18),　c　=　20.204(3)　Å,　β　=　105.692(2)°,　V　=　6015.0(14)　Å3,　Z　=　4,　Dc　=　2.473　g/cm3,　M　r　=　2239.68,　F(000)　=　4432,　R　=　0.0725,　wR　=　0.1524　and　GOOF　=　1.095.　The　metaloxo　cluster　contains　a　novel　six-capped　pesudo-Keggin　structure　unit　which　encloses　a　disorder　PO43-　guest.

Keyword：

Hydrothermal synthesis; Metal-oxo cluster; Pesudo-Keggin structure; Six-capped

Community：

[ 1 ] [Xiang, Y.]Department of Chemistry, Fuzhou University, Fuzhou 350002, China
[ 2 ] [Zhang, L.-W.]Department of Chemistry, Fuzhou University, Fuzhou 350002, China
[ 3 ] [Chen, W.-H.]Department of Chemistry, Fuzhou University, Fuzhou 350002, China
[ 4 ] [Chen, J.-Z.]Department of Chemistry, Fuzhou University, Fuzhou 350002, China
[ 5 ] [Zeng, Q.-X.]Department of Chemistry, Fuzhou University, Fuzhou 350002, China

Reprint 's Address：

曾庆新
[Zeng, Q.-X.]Department of Chemistry, Fuzhou University, Fuzhou 350002, China

Email：

frq_2002@yahoo.com.cn

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Source ：

Jiegou Huaxue

ISSN： 0254-5861

CN： 35-1112/TQ

Year： 2007

Issue： 4

Volume： 26

Page： 419-422

0 . 6 9 6

JCR@2007

5 . 9 0 0

JCR@2023

ESI Discipline： CHEMISTRY;

JCR Journal Grade：4

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ESI Highly Cited Papers on the List： 0 Unfold All

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